Smartphone-based colorimetric determination of fluoride anions using polymethacrylate optode

Bibliographische Detailangaben
Parent link:Talanta
Vol. 226.— 2021.— [122103, 5 p.]
Körperschaft: Национальный исследовательский Томский политехнический университет Инженерная школа неразрушающего контроля и безопасности Отделение контроля и диагностики
Weitere Verfasser: Saranchina N. V. Nadezhda Vasilievna, Slizhov Yu. G., Vodova Yu. M. Yuliya Mikhaylovna, Murzakasymova N. S. Nazgul Sattarkulovna, Iljina A. M. Anzhelika Mikhaylovna, Gavrilenko N. A. Nataljya Aleksandrovna, Gavrilenko M. A. Marina Aleksandrovna
Zusammenfassung:Title screen
We developed a new transparent polymer optode based on polymethacrylate with Zr(IV) and alizarin red complex immobilized into it for digital colorimetric and solid-phase spectrophotometric determination of fluoride anions. The matrix changes its colour from purple to yellow after it contacts fluoride anion. We developed a processing algorithm for coloured images which helps calculate mean value for the RGB colour-coordinate system in a selected optode image and translates it into a fluoride concentration value. The analytical signal of the suggested method has a linearity range of 0.1-30 mg•L-1 with the detection limit 0.03 mg•L-1. Compared to other methods, the modified polymethacrylate matrix is actually a ready-to-use colorimetric system offering rapid results for drinking water quality control.
Режим доступа: по договору с организацией-держателем ресурса
Sprache:Englisch
Veröffentlicht: 2021
Schlagworte:
Online-Zugang:https://doi.org/10.1016/j.talanta.2021.122103
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665147
Beschreibung
Zusammenfassung:Title screen
We developed a new transparent polymer optode based on polymethacrylate with Zr(IV) and alizarin red complex immobilized into it for digital colorimetric and solid-phase spectrophotometric determination of fluoride anions. The matrix changes its colour from purple to yellow after it contacts fluoride anion. We developed a processing algorithm for coloured images which helps calculate mean value for the RGB colour-coordinate system in a selected optode image and translates it into a fluoride concentration value. The analytical signal of the suggested method has a linearity range of 0.1-30 mg•L-1 with the detection limit 0.03 mg•L-1. Compared to other methods, the modified polymethacrylate matrix is actually a ready-to-use colorimetric system offering rapid results for drinking water quality control.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.talanta.2021.122103