MIL-101(Cr) for CO2 Conversion into Cyclic Carbonates, Under Solvent and Co-Catalyst Free Mild Reaction Conditions; Catalysts; Vol. 10, iss. 4
| Parent link: | Catalysts Vol. 10, iss. 4.— 2020.— [453, 12 p.] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , |
| Summary: | Title screen Mild reaction conditions (nearly room temperature and atmospheric CO2 pressure) for the cycloaddition of CO2 with epoxides to produce cyclic carbonates were investigated applying MIL-101(Cr) as a catalyst. The MIL-101 catalyst contains strong acid sites, which promote the ring-opening of the epoxide substrate. Moreover, the high surface area, enabling the adsorption of more CO2 (substrate), combined with a large pore size of the catalyst is essential for the catalytic performance. Additionally, epoxide substrates bearing electron-withdrawing substituents or having a low boiling point demonstrated an excellent conversion towards the cyclic carbonates. MIL-101(Cr) for the cycloaddition of carbon dioxide with epoxides is demonstrated to be a robust and stable catalyst able to be re-used at least five times without loss in activity. |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://doi.org/10.3390/catal10040453 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665032 |
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| 200 | 1 | |a MIL-101(Cr) for CO2 Conversion into Cyclic Carbonates, Under Solvent and Co-Catalyst Free Mild Reaction Conditions |f E. Akimana, J. Wang, N. V. Likhanova [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 53 tit.] | ||
| 330 | |a Mild reaction conditions (nearly room temperature and atmospheric CO2 pressure) for the cycloaddition of CO2 with epoxides to produce cyclic carbonates were investigated applying MIL-101(Cr) as a catalyst. The MIL-101 catalyst contains strong acid sites, which promote the ring-opening of the epoxide substrate. Moreover, the high surface area, enabling the adsorption of more CO2 (substrate), combined with a large pore size of the catalyst is essential for the catalytic performance. Additionally, epoxide substrates bearing electron-withdrawing substituents or having a low boiling point demonstrated an excellent conversion towards the cyclic carbonates. MIL-101(Cr) for the cycloaddition of carbon dioxide with epoxides is demonstrated to be a robust and stable catalyst able to be re-used at least five times without loss in activity. | ||
| 461 | |t Catalysts | ||
| 463 | |t Vol. 10, iss. 4 |v [453, 12 p.] |d 2020 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a MIL-101 | |
| 610 | 1 | |a heterogeneous catalyst | |
| 610 | 1 | |a CO2 cycloaddition | |
| 610 | 1 | |a carbonate | |
| 610 | 1 | |a ambient conditions | |
| 610 | 1 | |a гетерогенные катализаторы | |
| 610 | 1 | |a карбонаты | |
| 610 | 1 | |a окружающая среда | |
| 701 | 1 | |a Akimana |b E. |g Emmanuelia | |
| 701 | 1 | |a Wang |b J. |g Jichao | |
| 701 | 1 | |a Likhanova |b N. V. |g Nataljya Vladimirovna | |
| 701 | 0 | |a Chaemchuen Somboon |c chemist-technologist |c researcher at Tomsk Polytechnic University, Ph.D |f 1984- |3 (RuTPU)RU\TPU\pers\42620 | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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| 856 | 4 | |u https://doi.org/10.3390/catal10040453 | |
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