Iron Oxide and Iron Sulfide Films Prepared for Dye-Sensitized Solar Cells

Dades bibliogràfiques
Parent link:Materials
Vol. 13, iss. 8.— 2020.— [1797, 10 p.]
Altres autors: Tuharin K. Kostyantyn, Turek Z. Zdenek, Zanaska M. Michal, Kudrna P. Pavel, Tichy M. Milan
Sumari:Title screen
In this paper, the prospects of iron oxide films and their sulfidation for dye-sensitized solar cells (DSSC) are reviewed. Iron oxide thin films were prepared by hollow cathode plasma jet (HCPJ) sputtering, with an admixture of oxygen in the argon working gas and with an iron nozzle as the sputtering target. The discharge was powered by a constant current source in continuous mode and by a constant voltage source in pulsed mode. Plasma composition was measured by an energy-resolved mass spectrometer. Moreover, secondary electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), absorption and Raman spectra of the films are presented. Strong correlation between the color of the iron oxide film and its phase composition was revealed. Iron oxide films were sulfided at 350 °C. A relatively clean pyrite phase was obtained from the magnetite, while the marcasite with admixture of the pyrite phase was obtained from the hematite. Low influence of sulfidation on the films’ microstructure was demonstrated.
Idioma:anglès
Publicat: 2020
Matèries:
Accés en línia:https://doi.org/10.3390/ma13081797
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664995

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300 |a Title screen 
320 |a [References: 16 tit.] 
330 |a In this paper, the prospects of iron oxide films and their sulfidation for dye-sensitized solar cells (DSSC) are reviewed. Iron oxide thin films were prepared by hollow cathode plasma jet (HCPJ) sputtering, with an admixture of oxygen in the argon working gas and with an iron nozzle as the sputtering target. The discharge was powered by a constant current source in continuous mode and by a constant voltage source in pulsed mode. Plasma composition was measured by an energy-resolved mass spectrometer. Moreover, secondary electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), absorption and Raman spectra of the films are presented. Strong correlation between the color of the iron oxide film and its phase composition was revealed. Iron oxide films were sulfided at 350 °C. A relatively clean pyrite phase was obtained from the magnetite, while the marcasite with admixture of the pyrite phase was obtained from the hematite. Low influence of sulfidation on the films’ microstructure was demonstrated. 
461 |t Materials 
463 |t Vol. 13, iss. 8  |v [1797, 10 p.]  |d 2020 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a hollow cathode plasma jet 
610 1 |a iron oxide 
610 1 |a iron sulfide 
610 1 |a absorption spectroscopy 
610 1 |a dye-sensitized solar cell 
610 1 |a плазменная струя 
610 1 |a оксид железа 
610 1 |a абсорбционная спектроскопия 
610 1 |a солнечные элементы 
701 1 |a Tuharin  |b K.  |g Kostyantyn 
701 1 |a Turek  |b Z.  |g Zdenek 
701 1 |a Zanaska  |b M.  |g Michal 
701 1 |a Kudrna  |b P.  |g Pavel 
701 1 |a Tichy  |b M.  |c chemist  |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences  |f 1947-  |g Milan  |3 (RuTPU)RU\TPU\pers\35771 
801 2 |a RU  |b 63413507  |c 20210616  |g RCR 
856 4 |u https://doi.org/10.3390/ma13081797 
942 |c CF