Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst
| Parent link: | Materials Science Forum Vol. 917.— 2018.— [P. 122-126] |
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| निगमित लेखकों: | , |
| अन्य लेखक: | , , , |
| सारांश: | Title screen The way to produce the nanostructured carbon filaments via H2-assisted catalytic decomposition of CF2Cl2 over self-organizing Ni-based catalyst has been reported. The self-organizing 6%Ni/CNM catalyst, where CNM is a carbon nanomaterial, resulted from carbon erosion of bulk Ni-Cr alloy (nichrome) in C2H4Cl2 vapors was also shown to be effective for catalytic chemical vapor deposition of CF2Cl2 with formation of bimodal carbon structures. It was demonstrated that interaction of nichrome with CF2Cl2/H2 reaction mixture at 600 °C leads to its rapid disintegration caused by carbon erosion to form disperse active Ni-particles catalyzing the growth of carbon filaments. The resulted filamentous carbon material is characterized with high textural parameters. Режим доступа: по договору с организацией-держателем ресурса |
| भाषा: | अंग्रेज़ी |
| प्रकाशित: |
2018
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| विषय: | |
| ऑनलाइन पहुंच: | https://doi.org/10.4028/www.scientific.net/MSF.917.157 |
| स्वरूप: | इलेक्ट्रोनिक पुस्तक अध्याय |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664800 |
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| 200 | 1 | |a Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst |f Yu. A. Bauman, I. V. Mishakov, D. V. Korneev, A. A. Vedyagin | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 330 | |a The way to produce the nanostructured carbon filaments via H2-assisted catalytic decomposition of CF2Cl2 over self-organizing Ni-based catalyst has been reported. The self-organizing 6%Ni/CNM catalyst, where CNM is a carbon nanomaterial, resulted from carbon erosion of bulk Ni-Cr alloy (nichrome) in C2H4Cl2 vapors was also shown to be effective for catalytic chemical vapor deposition of CF2Cl2 with formation of bimodal carbon structures. It was demonstrated that interaction of nichrome with CF2Cl2/H2 reaction mixture at 600 °C leads to its rapid disintegration caused by carbon erosion to form disperse active Ni-particles catalyzing the growth of carbon filaments. The resulted filamentous carbon material is characterized with high textural parameters. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 0 | |0 (RuTPU)RU\TPU\network\24092 |t Materials Science Forum | |
| 463 | |t Vol. 917 |v [P. 122-126] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a 1,2-dichloroethane | |
| 610 | 1 | |a bulk alloys | |
| 610 | 1 | |a carbon erosion | |
| 610 | 1 | |a carbon fibers | |
| 610 | 1 | |a catalytic chemical vapor deposition | |
| 610 | 1 | |a CFC-12 | |
| 610 | 1 | |a halogenated hydrocarbons | |
| 610 | 1 | |a nichrome | |
| 610 | 1 | |a сплавы | |
| 610 | 1 | |a эрозия | |
| 610 | 1 | |a углеродные волокна | |
| 610 | 1 | |a химическое осаждение | |
| 610 | 1 | |a паровые фазы | |
| 610 | 1 | |a углеводороды | |
| 701 | 1 | |a Bauman |b Yu. A. |g Yury Anatoljevich | |
| 701 | 1 | |a Mishakov |b I. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, candidate of chemical sciences |f 1977- |g Iljya Vladimirovich |3 (RuTPU)RU\TPU\pers\36375 | |
| 701 | 1 | |a Korneev |b D. V. |g Denis | |
| 701 | 1 | |a Vedyagin |b A. A. |c Chemist |c Chief Expert of Tomsk Polytechnic University, Candidate of chemical sciences |f 1975- |g Aleksey Anatolievich |3 (RuTPU)RU\TPU\pers\36694 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа энергетики |b Научно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова) |3 (RuTPU)RU\TPU\col\23504 |
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| 856 | 4 | |u https://doi.org/10.4028/www.scientific.net/MSF.917.157 | |
| 942 | |c CF | ||