An Analysis of Vibrations and Rotations in the First Hydrogen Sulfide Hexade: the 4ν2 H322S Band; Optics and Spectroscopy; Vol. 129, iss. 1

An Analysis of Vibrations and Rotations in the First Hydrogen Sulfide Hexade: the 4ν2 H322S Band; Optics and Spectroscopy; Vol. 129, iss. 1

Bibliographische Detailangaben
Parent link:Optics and Spectroscopy
Vol. 129, iss. 1.— 2021.— [P. 6-11]
1. Verfasser: Zhang Fangce
Körperschaft: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Weitere Verfasser: Raspopova N. I. Natalya Ivanovna
Zusammenfassung:Title screen
The infrared spectrum of the H2S molecule is recorded using a Bruker IFS 125HR Fourier transform spectrometer and studied in the range of 4500-5000 cm-1, in which the first hexad of bands of interacting states of the hydrogen sulfide molecule is located (in this particular case, weak band 4ν2ν2 is studied). Four hundred transitions with maximum quantum numbers of JmaxJmax = 17 and KmaxaKamax = 8 are assigned in the experimental spectrum. These transitions correspond to one hundred thirty two upper vibration-rotation energy levels. The obtained data are analyzed using Watson's model of the effective Hamiltonian. By solving the inverse spectroscopic problem, a set of twenty eight spectroscopic parameters was obtained, which reproduces the initial experimental data with a standard deviation of drmsdrms= 3.5 × 10-4 cm-1.
Режим доступа: по договору с организацией-держателем ресурса
Sprache:Englisch
Veröffentlicht: 2021
Schlagworte:
электронный ресурс
труды учёных ТПУ
molecular spectroscopy
first hydrogen sulfide hexade
vibration-rotation Hamiltonian
молекулярная спектроскопия
гамильтонианы
Online-Zugang:https://doi.org/10.1134/S0030400X21010045
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664699

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