Mono- and dinuclear organotin(IV) complexes for solvent free cycloaddition of CO2 to epoxides at ambient pressure; Journal of CO2 Utilization; Vol. 28

Mono- and dinuclear organotin(IV) complexes for solvent free cycloaddition of CO2 to epoxides at ambient pressure; Journal of CO2 Utilization; Vol. 28

Bibliographic Details
Parent link:Journal of CO2 Utilization
Vol. 28.— 2018.— [P. 313-318]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors: Khattak Z. A. K. Zafar, Younus H. A. Hussein, Ahmad N. Nazir, Yu Baoyi, Ullah Habib, Suleman S. Suleman, Chughtai A. H. Adeel, Moosavifar M. Maryam, Chaemchuen S. Somboon, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Novel mono- and dinuclear dimethyltin(IV) complexes were synthesized using tridentate Schiff base ligands, derived from 2-amino-2-hydroxymethyl-propane-1,3-diol and various aldehydes. These diorganotin(IV) compounds displayed good catalytic activity for solvent-free cycloaddition of CO2 to epoxides at ambient pressure. These catalysts efficiently completed the insertion of CO2 to various epoxides at low catalyst loadings (0.1-1.0 mol%) in 1-6 hours giving high values of TONs around 1000. The catalyst further usability for three continuous reaction runs in the reaction mixture gives the same activity revealing the remarkable stability of these compounds under the given reaction conditions. Therefore, organotin(IV) complexes are efficient catalysts for the synthesis of the industrially important cyclic carbonates from epoxides at ambient pressure under solvent-free conditions.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2018
Subjects:
электронный ресурс
труды учёных ТПУ
homogeneous catalysis
organotin complexes
solvent-free
ambient pressure
CO2cycloaddition
гомогенный катализ
растворители
давление
внешняя среда
циклоприсоединение
эпоксиды
Online Access:https://doi.org/10.1016/j.jcou.2018.10.014
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664472

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