Preparation, structure, and oxidative reactivity of (dichloroiodo)pyridines: recyclable hypervalent iodine reagents; ARKIVOC; Vol. 2018, iss. part ii

Preparation, structure, and oxidative reactivity of (dichloroiodo)pyridines: recyclable hypervalent iodine reagents; ARKIVOC; Vol. 2018, iss. part ii

Dades bibliogràfiques
Parent link:	ARKIVOC Vol. 2018, iss. part ii.— 2018.— [P. 40-49]
Autor corporatiu:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Altres autors:	Yoshimura A. Akira, Nguyen K. C. Khiem, Nemykin V. N. Victor, Zhdankin V. V. Viktor Vladimirovich
Sumari:	Title screen New pyridine-based hypervalent iodine reagents, (dichloroiodo)pyridines, were prepared by chlorination of 2-, 3-, or 4-iodopyridines with NaOCl-HCl at room temperature. Structures of 2-(dichloroiodo)pyridine and 2- (dichloroiodo)-3-propoxypyridine were established by X-ray crystallography. The new (dichloroiodo)pyridines can be used as efficient reagents for oxidation of alcohols to carbonyl compounds and also as chlorinating reagents. The reduced form of the reagents such as 2-iodo-3-propoxypyridine, can be recovered from the reaction mixture in good yields by an acid-base liquid-liquid biphasic protocol.
Idioma:	anglès
Publicat:	2018
Matèries:	электронный ресурс труды учёных ТПУ структуры окислительная способность пиридины реагенты гипервалентный йод хлорирование
Accés en línia:	https://doi.org/10.24820/ark.5550190.p010.279
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664466

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