SIMes/PCy3 mixed ligand-coordinated alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Applied Organometallic Chemistry; Vol. 32, iss. 12

SIMes/PCy3 mixed ligand-coordinated alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity; Applied Organometallic Chemistry; Vol. 32, iss. 12

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Parent link:	Applied Organometallic Chemistry Vol. 32, iss. 12.— 2018.— [e4548, 8 p.]
Tác giả của công ty:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Tác giả khác:	Yu Baoyi, Li Yanli, He Xu, Hamad F. B. Fatma, Ding Fu, Van H. K. Hecke Kristo, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Verpoort F. V. K. Frensis Valter Kornelius
Tóm tắt:	Title screen We report on the synthesis and characterization of SIMes/PCy3 mixed ligand coordinated second generation ruthenium catalysts, bearing various 3-alkyl-1-indenylidene ligands, denoted as RuCl2(3-alkyl-1-indenylidene)(SIMes)(PCy3), in which alkyl is isopropyl (4f), tert-butyl (4g) or cyclohexyl (4h). The characterization of complexes 4f-4h was performed using infrared spectroscopy, elemental analysis, high-resolution mass spectrometry and NMR spectroscopy. In addition, the configuration of complexes 4f and 4g was analyzed using single crystal X-ray diffraction analysis. The catalytic activities of 4f-4h were evaluated in the olefin metathesis reaction of the ring-closing metathesis of diethyl diallylmalonate, and the ring-opening metathesis polymerization of cis,cis-cyclooctadiene in comparison with the reference complex 4a. The results reveal that all complexes 4a and 4f-4h exhibit similar catalytic activity towards the tested substrates. Careful analysis of the catalyst performance and single-crystal X-ray diffraction data of the obtained complexes reveals that the steric modification on the 3-alkyl group shows a negligible influence on the ligand congestion around the ruthenium center as well as on the catalytic activities in the metathesis reactions.
Ngôn ngữ:	Tiếng Anh
Được phát hành:	2018
Những chủ đề:	электронный ресурс труды учёных ТПУ homogeneous catalysis indenylidene olefin metathesis ruthenium catalysts гомогенный катализ метатезис олефины рутений катализаторы
Truy cập trực tuyến:	https://doi.org/10.1002/aoc.4548
Định dạng:	Điện tử Chương của sách
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664392

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