Mutual influence of hydrogen and vacancies in α-zirconium on the energy of their interaction with metal; Physics of the Solid State; Vol. 60, iss. 1

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Parent link:Physics of the Solid State
Vol. 60, iss. 1.— 2018.— [P. 10-19]
Hlavní autor: Svyatkin L. A. Leonid Aleksandrovich
Korporativní autor: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение экспериментальной физики
Další autoři: Koroteev Yu. M. Yuri Mikhailovich, Chernov I. P. Ivan Petrovich
Shrnutí:Title screen
We presents a first-principles investigation on the interaction energy of hydrogen and vacancies with ?-zirconium. It is established that the presence of vacancies in zirconium increases the hydrogen–metal binding energy; the presence of hydrogen in the zirconium lattice reduces the vacancy formation energy. It is shown that hydrogen and vacancies in zirconium form complexes that considerably distort the metal lattice. The increase in the covalency degree of the metal–metal and hydrogen–metal bounds is observed in the vicinity of these complexes.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2018
Témata:
On-line přístup:https://doi.org/10.1134/S1063783418010262
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664377

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330 |a We presents a first-principles investigation on the interaction energy of hydrogen and vacancies with ?-zirconium. It is established that the presence of vacancies in zirconium increases the hydrogen–metal binding energy; the presence of hydrogen in the zirconium lattice reduces the vacancy formation energy. It is shown that hydrogen and vacancies in zirconium form complexes that considerably distort the metal lattice. The increase in the covalency degree of the metal–metal and hydrogen–metal bounds is observed in the vicinity of these complexes. 
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