First Study of the Thermal and Storage Stability of Arenediazonium Triflates Comparing to 4-Nitrobenzenediazonium Tosylate and Tetrafluoroborate by Calorimetric Methods; Organic Process Research and Development; Vol. 23, iss. 11

First Study of the Thermal and Storage Stability of Arenediazonium Triflates Comparing to 4-Nitrobenzenediazonium Tosylate and Tetrafluoroborate by Calorimetric Methods; Organic Process Research and Development; Vol. 23, iss. 11

Bibliografske podrobnosti
Parent link:Organic Process Research and Development
Vol. 23, iss. 11.— 2019.— [P. 2405–2415]
Korporativna značnica: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
Drugi avtorji: Bondarev A. A. Aleksandr Aleksandrovich, Naumov E. V. Evgeny Vladimirovich, Kasanova A. Asiya, Krasnokutskaya E. A . Elena Aleksandrovna, Stankevich K. S. Ksenia Sergeevna, Filimonov V. D. Viktor Dmitrievich
Izvleček:Title screen
Herein, for the first time, using isothermal flow calorimetry and differential scanning calorimetry (DSC)/thermal gravimetric analysis (TGA), we have determined the thermal decomposition energies for the number of solid arenediazonium triflates comparing to 4-nitrobenzene tosylate and 4-nitrobenzentetrafluoroborate. The kinetics of thermal decomposition, activation energies, and half-lives of the studied diazonium salts (DSs) were found. Using gas chromatography–mass spectrometry (MS) and liquid chromatography–MS, we have elucidated the products formed during thermolysis of the investigated DSs. By density functional theory quantum chemical calculations at the B3LYP/aug-cc-pVDZ level of theory, we simulated the thermodynamics of decomposition reactions proceeding via substitution of the diazonium group by corresponding nucleophiles. The method applied predicted the decomposition energies of all the studied compounds fairly precise, except for 2-nitrobenzene diazonium triflate. It has been found that 4-nitrobenzene diazonium triflate has increased storage stability under normal conditions comparing to the corresponding tosylate and tetrafluoroborate. The experimental and theoretical results demonstrated that comparing to DSC/TGA, isothermal flow calorimetry more adequately reflects the energetics of the thermal decomposition of DSs and their storage stability under normal conditions.
Режим доступа: по договору с организацией-держателем ресурса
Jezik:angleščina
Izdano: 2019
Teme:
труды учёных ТПУ
электронный ресурс
arenediazonium salts
stability
isothermal flow calorimetry
quantum chemical calculation
thermolysis
арендиазониевые соли
стабильность
калориметры
квантово-химический расчет
термолиз
Online dostop:https://doi.org/10.1021/acs.oprd.9b00307
Format: Elektronski Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=664231

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