Chemical fixation of carbon dioxide catalyzed via cobalt (III) ONO pincer ligated complexes; Communications Chemistry; Vol. 2

Chemical fixation of carbon dioxide catalyzed via cobalt (III) ONO pincer ligated complexes; Communications Chemistry; Vol. 2

Detalles Bibliográficos
Parent link:Communications Chemistry
Vol. 2.— 2019.— [42, 9 p.]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Otros Autores: Ullah H. Habib, Mousavi B. Bibimaryam, Younus H. A. Hussein, Khattak Z. A. K. Zafar, Chaemchuen Somboon, Verpoort F. V. K. Frensis Valter Kornelius
Sumario:Title screen
Chemical insertion of carbon dioxide into epoxides under ambient conditions has become one of the most important methods for the construction of cyclic organic carbonates. Various active salen, salophen, and phenolate ligand based complexes have been reported for the synthesis of cyclic organic carbonates. Here we demonstrate a series of ONO pincer type cobalt (III) complexes as efficient catalysts for the cycloaddition of carbon dioxide to epoxides in neat conditions at atmospheric pressure with and without co-catalyst. A turnover number of up to 200,000 under atmospheric pressure is achieved. Moreover, the in situ generated complex shows high activity and the catalyst can be reused for at least 11 cycles without any decline in catalytic performance.
Режим доступа: по договору с организацией-держателем ресурса
Lenguaje:inglés
Publicado: 2019
Materias:
электронный ресурс
труды учёных ТПУ
green chemistry
homogeneous catalysis
organometallic chemistry
chemical synthesis
гомогенный катализ
металлоорганическая химия
химический синтез
Acceso en línea:https://doi.org/10.1038/s42004-019-0139-y
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=663788

Ejemplares similares

Ejemplares similares