Conjugated mesoporous polyazobenzene–Pd(II) composite: A potential catalyst for visible-light-induced Sonogashira coupling; Journal of Catalysis; Vol. 377

Conjugated mesoporous polyazobenzene–Pd(II) composite: A potential catalyst for visible-light-induced Sonogashira coupling; Journal of Catalysis; Vol. 377

Λεπτομέρειες βιβλιογραφικής εγγραφής
Parent link:Journal of Catalysis
Vol. 377.— 2019.— [P. 183-189]
Συγγραφή απο Οργανισμό/Αρχή: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Άλλοι συγγραφείς: Nath I. Ipsita, Chakraborty J. Jeet, Khan A. Anish, Arshad M. N. Muhammad, Azum N. Naved, Rab M. A. Malik, Asiri A. M. Abdullah, Alamry Kh. A. Khalid, Verpoort F. V. K. Frensis Valter Kornelius
Περίληψη:Title screen
We herein report the direct harnessing of visible light energy by a novel semiconducting azobenzene-based colloidal porous organic polymer, B3-Azo4 amenable to post-synthetic Pd(II)-complexation for photo-induced Sonogashira coupling using polymer???metal energy transfer process. Completely mesoporous nano-sized particles of the obtained organic network manifested excellent Pd(II) coordinating ability and afforded desired catalytic products at room temperature under aerobic condition in aqueous medium. The protocol remained valid for different aromatic and aliphatic substrates as well. A possible reaction mechanism for photo-mediated Sonogashira coupling catalyzed by Pd-B3-Azo4 is also proposed.
Режим доступа: по договору с организацией-держателем ресурса
Γλώσσα:Αγγλικά
Έκδοση: 2019
Θέματα:
электронный ресурс
труды учёных ТПУ
azobenzene
colloidal porous organic polymer
energy transfer
visible and sunlight induced
sonogashira
mechanism
Διαθέσιμο Online:https://doi.org/10.1016/j.jcat.2019.07.031
Μορφή: Ηλεκτρονική πηγή Κεφάλαιο βιβλίου
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=663787
Περιγραφή
Περίληψη:Title screen
We herein report the direct harnessing of visible light energy by a novel semiconducting azobenzene-based colloidal porous organic polymer, B3-Azo4 amenable to post-synthetic Pd(II)-complexation for photo-induced Sonogashira coupling using polymer???metal energy transfer process. Completely mesoporous nano-sized particles of the obtained organic network manifested excellent Pd(II) coordinating ability and afforded desired catalytic products at room temperature under aerobic condition in aqueous medium. The protocol remained valid for different aromatic and aliphatic substrates as well. A possible reaction mechanism for photo-mediated Sonogashira coupling catalyzed by Pd-B3-Azo4 is also proposed.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.jcat.2019.07.031

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