Plasma Dynamic Synthesis of Nanocrystalline WC1 – x and the Dependence of the Product Structure on the Ratio of Precursors

Bibliographic Details
Parent link:Technical Physics
Vol. 65, iss. 12.— 2020.— [P. 2007-2015]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Отделение электроэнергетики и электротехники
Other Authors: Sivkov A. A. Aleksandr Anatolyevich, Shanenkov I. I. Ivan Igorevich, Shanenkova Yu. L. Yuliya Leonidovna, Rakhmatullin I. A. Ilyas Aminovich, Ivashutenko A. S. Alexander Sergeevich, Nikitin D. S. Dmitry Sergeevich, Nassyrbayev A. Artur
Summary:Title screen
The results of plasma dynamic synthesis of nanocrystalline cubic tungsten carbide using a system based on a coaxial magnetoplasma accelerator are presented. It is found that an atomic ratio of C/W precursors of about 2.5 is necessary to achieve the maximum yield of the unique cubic phase of tungsten carbide WC1 – x (up to 95%). The synthesized materials are analyzed by transmission electron microscopy to assess the formation of the structure of nanocrystalline particles depending on the ratio of carbon and tungsten filling. It is found that particles with a core–shell structure are formed in the system, and the thickness of the shells increases with an increase in the amount of carbon in the mixture of initial components.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2020
Subjects:
Online Access:https://doi.org/10.1134/S1063784220120269
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=663409
Description
Summary:Title screen
The results of plasma dynamic synthesis of nanocrystalline cubic tungsten carbide using a system based on a coaxial magnetoplasma accelerator are presented. It is found that an atomic ratio of C/W precursors of about 2.5 is necessary to achieve the maximum yield of the unique cubic phase of tungsten carbide WC1 – x (up to 95%). The synthesized materials are analyzed by transmission electron microscopy to assess the formation of the structure of nanocrystalline particles depending on the ratio of carbon and tungsten filling. It is found that particles with a core–shell structure are formed in the system, and the thickness of the shells increases with an increase in the amount of carbon in the mixture of initial components.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1134/S1063784220120269