Taking the power of plasmon-assisted chemistry on copper NPs: Preparation and application of COFs nanostructures for CO2 sensing in water; Microporous and Mesoporous Materials; Vol. 309

Taking the power of plasmon-assisted chemistry on copper NPs: Preparation and application of COFs nanostructures for CO2 sensing in water; Microporous and Mesoporous Materials; Vol. 309

書誌詳細
Parent link:Microporous and Mesoporous Materials
Vol. 309.— 2020.— [110577, 8 p.]
団体著者: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
その他の著者: Guselnikova O. A. Olga Andreevna, Kalachyova E. Evgeniya, Elashnikov R. Roman, Cieslar M. Miroslav, Kolska Zd. Zdenka, Sajdl P. Petr, Postnikov P. S. Pavel Sergeevich, Svorcik V. Vaclav, Lyutakov O. Oleksy
要約:Title screen
In this contribution, we report a novel, mild, and energy efficient approach for the preparation of covalent organic frameworks (COFs) at ambient conditions. For the first time, powerful plasmonic chemistry was applied for the synthesis of carbon triazine framework (CTF-1) on copper nanoparticles (CuNPs) as an alternative to common synthetic procedures, which are restricted by harsh experimental conditions and low throughput. Plasmonic CuNPs were functionalized by 4-cyanophenyl groups, which were further used as anchoring groups for surface-assisted growth of CTF-1 under the illumination at wavelength corresponding to plasmon absorption band of CuNPs. Prepared CuNPs@CTF-1 structure exhibit core-shell nature and outstanding sensing properties for CO2 in water. In the next step, the copper core was dissolved, and resulting CTF-1 powder with high surface area was isolated. Generally, our pioneering work demonstrates the power of plasmonic chemistry for unpretentious COF synthesis performed in mild and cheap manner without any special apparatus and harsh conditions, as well as for the preparation of applied sensing material.
Режим доступа: по договору с организацией-держателем ресурса
言語:英語
出版事項: 2020
主題:
труды учёных ТПУ
электронный ресурс
plasmon catalysis
covalent-organic framework
sustainable chemistry
copper nanoparticles
CO2 sensor
плазмонные свойства
オンライン･アクセス:https://doi.org/10.1016/j.micromeso.2020.110577
フォーマット: 電子媒体 図書の章
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=663330

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