Effect of parylene C coating on the antibiocorrosive and mechanical properties of different magnesium alloys; Applied Surface Science; Vol. 427, Pt. A

Detalles Bibliográficos
Parent link:Applied Surface Science
Vol. 427, Pt. A.— 2018.— [P. 617-627]
Corporate Authors: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Лаборатория плазменных гибридных систем, Национальный исследовательский Томский политехнический университет Физико-технический институт Кафедра экспериментальной физики
Outros autores: Surmeneva M. A. Maria Alexandrovna, Vladesku A. Alina, Kotrut M. K. Mikhay Kosmin, Tyurin A. I. Aleksandr Ivanovich, Pirozhkova T. S. Tatjyana Sergeevna, Shuvarin I. A. Ivan Aleksandrovich, Elkin B. Bentsian, Oehr C. Christian, Surmenev R. A. Roman Anatolievich
Summary:Title screen
In this paper, parylene C coating with the thickness of 2 μm was deposited on different magnesium alloy substrates (AZ31, WE43 and AZ91). The structure and phase composition of parylene C coating was analysed by Fourier transformed infrared (FTIR) spectroscopy and X-ray diffraction (XRD). In addition, extensive surface characterization was done using atomic force microscopy. The corrosion performance of polymer-coated magnesium alloys was investigated by electrochemical measurements in Hanks' balanced salts solution that simulates bodily fluids at 37 ± 0.5 °C. The depth-dependent mechanical properties including Young's modulus and nanohardness of parylene C films were investigated using nanoindentation technique. The effect of the penetration depth on the properties on nano- and microscale level have been described in detail. The percentage of elastic recovery was used to characterize the elastic properties of the polymeric coatings. The results of XRD showed (020) preferred orientation of the monoclinic unit cell of the alpha phase of parylene C. The parylene C revealed a semicrystalline structure with nanocrystalline blocks of 4.9 nm. The parylene C film shows a uniform surface morphology with a higher roughness level at micro and nanoscales compared to magnesium alloy surfaces.
All of the uncoated substrates exhibited a low corrosion resistance compared to the coated samples, indicating that the corrosion resistance of the magnesium alloys could be improved by parylene C coating. The resulting average nanohardness and Young's modulus of the parylene C coatings deposited onto different substrates were in the range of 0.18-0.25 GPa and 4.19-5.14 GPa, respectively. Furthermore, a higher percentage of elastic recovery of the polymer coating indicated a higher elasticity as compared to the magnesium alloy surface. The polymer coating has revealed the ability to recover elastically. Therefore, parylene C coating can not only improve corrosion resistance, but also provide the ability to recover elastically, expanding the potential applications of this material to include various biointerface platforms.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglés
Publicado: 2018
Subjects:
Acceso en liña:https://doi.org/10.1016/j.apsusc.2017.08.066
Formato: MixedMaterials Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662942

MARC

LEADER 00000naa0a2200000 4500
001 662942
005 20250417130743.0
035 |a (RuTPU)RU\TPU\network\34110 
035 |a RU\TPU\network\23601 
090 |a 662942 
100 |a 20210113d2018 k||y0rusy50 ba 
101 0 |a eng 
102 |a NL 
135 |a drcn ---uucaa 
181 0 |a i  
182 0 |a b 
200 1 |a Effect of parylene C coating on the antibiocorrosive and mechanical properties of different magnesium alloys  |f M. A. Surmeneva [et al.] 
203 |a Text  |c electronic 
300 |a Title screen 
320 |a [References: 61 tit.] 
330 |a In this paper, parylene C coating with the thickness of 2 μm was deposited on different magnesium alloy substrates (AZ31, WE43 and AZ91). The structure and phase composition of parylene C coating was analysed by Fourier transformed infrared (FTIR) spectroscopy and X-ray diffraction (XRD). In addition, extensive surface characterization was done using atomic force microscopy. The corrosion performance of polymer-coated magnesium alloys was investigated by electrochemical measurements in Hanks' balanced salts solution that simulates bodily fluids at 37 ± 0.5 °C. The depth-dependent mechanical properties including Young's modulus and nanohardness of parylene C films were investigated using nanoindentation technique. The effect of the penetration depth on the properties on nano- and microscale level have been described in detail. The percentage of elastic recovery was used to characterize the elastic properties of the polymeric coatings. The results of XRD showed (020) preferred orientation of the monoclinic unit cell of the alpha phase of parylene C. The parylene C revealed a semicrystalline structure with nanocrystalline blocks of 4.9 nm. The parylene C film shows a uniform surface morphology with a higher roughness level at micro and nanoscales compared to magnesium alloy surfaces. 
330 |a All of the uncoated substrates exhibited a low corrosion resistance compared to the coated samples, indicating that the corrosion resistance of the magnesium alloys could be improved by parylene C coating. The resulting average nanohardness and Young's modulus of the parylene C coatings deposited onto different substrates were in the range of 0.18-0.25 GPa and 4.19-5.14 GPa, respectively. Furthermore, a higher percentage of elastic recovery of the polymer coating indicated a higher elasticity as compared to the magnesium alloy surface. The polymer coating has revealed the ability to recover elastically. Therefore, parylene C coating can not only improve corrosion resistance, but also provide the ability to recover elastically, expanding the potential applications of this material to include various biointerface platforms. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Applied Surface Science 
463 |t Vol. 427, Pt. A  |v [P. 617-627]  |d 2018 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a биоразлагаемые материалы 
610 1 |a биоразлагаемые полимеры 
610 1 |a упругость 
610 1 |a магниевые сплавы 
610 1 |a нанотвердость 
701 1 |a Surmeneva  |b M. A.  |c specialist in the field of material science  |c engineer-researcher of Tomsk Polytechnic University, Associate Scientist  |f 1984-  |g Maria Alexandrovna  |3 (RuTPU)RU\TPU\pers\31894  |9 15966 
701 1 |a Vladesku  |b A.  |c Romanian specialists in the field of biomaterials  |c researcher of Tomsk Polytechnic University, candidate of biological Sciences  |f 1977-  |g Alina  |3 (RuTPU)RU\TPU\pers\39940  |9 21177 
701 1 |a Kotrut  |b M. K.  |c physicist  |c physicist Professor Tomsk Polytechnic University, Ph.D.  |f 1977-  |g Mikhay Kosmin  |3 (RuTPU)RU\TPU\pers\37467  |9 20354 
701 1 |a Tyurin  |b A. I.  |g Aleksandr Ivanovich 
701 1 |a Pirozhkova  |b T. S.  |g Tatjyana Sergeevna 
701 1 |a Shuvarin  |b I. A.  |g Ivan Aleksandrovich 
701 1 |a Elkin  |b B.  |g Bentsian 
701 1 |a Oehr  |b C.  |g Christian 
701 1 |a Surmenev  |b R. A.  |c physicist  |c Associate Professor of Tomsk Polytechnic University, Senior researcher, Candidate of physical and mathematical sciences  |f 1982-  |g Roman Anatolievich  |3 (RuTPU)RU\TPU\pers\31885  |9 15957 
712 0 2 |a Национальный исследовательский Томский политехнический университет  |b Инженерная школа ядерных технологий  |b Лаборатория плазменных гибридных систем  |c (2017- )  |3 (RuTPU)RU\TPU\col\23381  |9 28304 
712 0 2 |a Национальный исследовательский Томский политехнический университет  |b Физико-технический институт  |b Кафедра экспериментальной физики  |3 (RuTPU)RU\TPU\col\21255  |9 27946 
801 2 |a RU  |b 63413507  |c 20210113  |g RCR 
850 |a 63413507 
856 4 |u https://doi.org/10.1016/j.apsusc.2017.08.066 
942 |c CF