Features of Epoxidation of Fatty Acid Methyl Esters in a Bubble Reactor; Russian Journal of Applied Chemistry; Vol. 93, iss. 5

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Parent link:Russian Journal of Applied Chemistry
Vol. 93, iss. 5.— 2020.— [P. 704-711]
Korporativní autor: Национальный исследовательский Томский политехнический университет Инженерная школа природных ресурсов Отделение химической инженерии
Další autoři: Sapunov V. N. Valentin Nikolaevich, Yudaev S. A. Sergey Aleksandrovich, Cherepanova A. D. Anna Dmitrievna, Ivashkina E. N. Elena Nikolaevna, Voronov M. S. Mikhail Sergeevich, Kozlovsky R. A. Roman Anatoljevich
Shrnutí:Title screen
The patterns of epoxidation of linoleic acid methyl ester in a mixture of methyl esters of sunfl ower oilfatty acids with atmospheric oxygen in a bubble column reactor are analyzed at various feed rates of the gas phase.It was found that the oxidation process takes place in the transition region, under diff usion control conditions. Thecontributions of the diff usion and kinetic components to the rate of oxidative epoxidation of fatty acid methyl estersare determined. It was established that the selectivity of the epoxidation reaction decreases with the transition ofthe oxidation process from the diff usion region to the kinetic.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2020
Témata:
On-line přístup:https://doi.org/10.1134/S1070427220050110
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662864
Popis
Shrnutí:Title screen
The patterns of epoxidation of linoleic acid methyl ester in a mixture of methyl esters of sunfl ower oilfatty acids with atmospheric oxygen in a bubble column reactor are analyzed at various feed rates of the gas phase.It was found that the oxidation process takes place in the transition region, under diff usion control conditions. Thecontributions of the diff usion and kinetic components to the rate of oxidative epoxidation of fatty acid methyl estersare determined. It was established that the selectivity of the epoxidation reaction decreases with the transition ofthe oxidation process from the diff usion region to the kinetic.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1134/S1070427220050110