Beyond graphene oxide: laser engineering functionalized graphene for flexible electronics; Materials Horizons; Vol. 7, iss. 4

Dades bibliogràfiques
Parent link:Materials Horizons
Vol. 7, iss. 4.— 2020.— [P. 951-1196]
Autor corporatiu: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий, Национальный исследовательский Томский политехнический университет Школа инженерного предпринимательства, Национальный исследовательский Томский политехнический университет Инженерная школа природных ресурсов Отделение химической инженерии, Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Altres autors: Rodriguez (Rodriges) Contreras R. D. Raul David, Khalelov A. A. Alimzhan Alikzhanovich, Postnikov P. S. Pavel Sergeevich, Lipovka A. A. Anna Anatolyevna, Dorozhko E. V. Elena Vladimirovna, Amin I. Ihsan, Murastov G. V. Gennadiy Viktorovich, Chen Jin-Ju, Sheng Wenbo, Trusova M. E. Marina Evgenievna, Chehimi M. M. Mohamed Mehdi, Sheremet E. S. Evgeniya Sergeevna
Sumari:Title screen
Carbon nanomaterials, especially graphene, are promising due to their abundance and the possibility to exploit them in lightweight, flexible, and wearable electronics enabling paradigms such as the Internet of Things. However, conventional methods to synthesize and integrate graphene into functional materials and flexible devices are either hazardous, time demanding, or excessively energy-consuming. To overcome these issues, here we propose a new concept based on the laser processing of single-layer diazonium-functionalized graphene. This is a safe, inexpensive, and environmentally-friendly method making it a competitive alternative for graphene-device fabrication. Flexible chemiresistors exhibit sensitivity for breath (water vapor and CO2) and ethanol detection up to 1500% higher than laser-reduced graphene oxide devices. We attribute this enhanced sensitivity to an optimal balance between structural defects and electrical conductivity. Flexible electronic circuits demonstrate a superb resilience against scratching and high current stability up to 98% with durability against 180° bending cycles for continuous operation of several weeks. This work can impact biomedical technology and electronics where tunable electrical conductivity, sensitivity, and mechanical stability are of uttermost importance.
Idioma:anglès
Publicat: 2020
Matèries:
Accés en línia:https://doi.org/10.1039/C9MH01950B
Format: MixedMaterials Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=662504

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200 1 |a Beyond graphene oxide: laser engineering functionalized graphene for flexible electronics  |f R. D. Rodriguez (Rodriges) Contreras, A. A. Khalelov, P. S. Postnikov [et al.] 
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330 |a Carbon nanomaterials, especially graphene, are promising due to their abundance and the possibility to exploit them in lightweight, flexible, and wearable electronics enabling paradigms such as the Internet of Things. However, conventional methods to synthesize and integrate graphene into functional materials and flexible devices are either hazardous, time demanding, or excessively energy-consuming. To overcome these issues, here we propose a new concept based on the laser processing of single-layer diazonium-functionalized graphene. This is a safe, inexpensive, and environmentally-friendly method making it a competitive alternative for graphene-device fabrication. Flexible chemiresistors exhibit sensitivity for breath (water vapor and CO2) and ethanol detection up to 1500% higher than laser-reduced graphene oxide devices. We attribute this enhanced sensitivity to an optimal balance between structural defects and electrical conductivity. Flexible electronic circuits demonstrate a superb resilience against scratching and high current stability up to 98% with durability against 180° bending cycles for continuous operation of several weeks. This work can impact biomedical technology and electronics where tunable electrical conductivity, sensitivity, and mechanical stability are of uttermost importance. 
461 |t Materials Horizons 
463 |t Vol. 7, iss. 4  |v [P. 951-1196]  |d 2020 
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701 1 |a Rodriguez (Rodriges) Contreras  |b R. D.  |c Venezuelan physicist, doctor of science  |c Professor of Tomsk Polytechnic University  |f 1982-  |g Raul David  |3 (RuTPU)RU\TPU\pers\39942  |9 21179 
701 1 |a Khalelov  |b A. A.  |g Alimzhan Alikzhanovich 
701 1 |a Postnikov  |b P. S.  |c organic chemist  |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1984-  |g Pavel Sergeevich  |3 (RuTPU)RU\TPU\pers\31287  |9 15465 
701 1 |a Lipovka  |b A. A.  |c chemist  |c Associate Scientist of Tomsk Polytechnic University  |f 1993-  |g Anna Anatolyevna  |3 (RuTPU)RU\TPU\pers\44078  |9 21753 
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701 1 |a Amin  |b I.  |g Ihsan 
701 1 |a Murastov  |b G. V.  |c Specialist in the field of lightning engineering  |c Assistant of the Department of Tomsk Polytechnic University  |f 1989-  |g Gennadiy Viktorovich  |3 (RuTPU)RU\TPU\pers\37695  |9 20489 
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