Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer; Polymer Science, Series C; Vol. 61, iss. 1
| Parent link: | Polymer Science, Series C Vol. 61, iss. 1.— 2019.— [P. 49-57] |
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| مؤلفون مشاركون: | , |
| مؤلفون آخرون: | , , , , , |
| الملخص: | Title screen In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures. Режим доступа: по договору с организацией-держателем ресурса |
| اللغة: | الإنجليزية |
| منشور في: |
2019
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| الموضوعات: | |
| الوصول للمادة أونلاين: | https://doi.org/10.1134/S1811238219010119 |
| التنسيق: | الكتروني فصل الكتاب |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=661170 |
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| 200 | 1 | |a Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer |f A. A. Lyapkov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 60 tit.] | ||
| 330 | |a In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Polymer Science, Series C | ||
| 463 | |t Vol. 61, iss. 1 |v [P. 49-57] |d 2019 | ||
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| 701 | 1 | |a Bozhenkova |b G. S. |c chemical engineer |c Associate Scientist, engineer of Tomsk Polytechnic University |f 1986- |g Galina Sergeevna |3 (RuTPU)RU\TPU\pers\32227 | |
| 701 | 1 | |a Smirnova |b N. A. |c Chemical Technologist |c engineer of Tomsk Polytechnic University |f 1990- |g Nataljya Aleksandrovna |3 (RuTPU)RU\TPU\pers\43099 | |
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