Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

التفاصيل البيبلوغرافية
Parent link:Polymer Science, Series C
Vol. 61, iss. 1.— 2019.— [P. 49-57]
مؤلفون مشاركون: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий, Национальный исследовательский Томский политехнический университет Инженерная школа природных ресурсов Отделение химической инженерии
مؤلفون آخرون: Lyapkov A. A. Aleksey Alekseevich, Bozhenkova G. S. Galina Sergeevna, Smirnova N. A. Nataljya Aleksandrovna, Prokudina N. I. Nailya Ilmirovna, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Verpoort F. V. K. Frensis Valter Kornelius
الملخص:Title screen
In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
Режим доступа: по договору с организацией-держателем ресурса
اللغة:الإنجليزية
منشور في: 2019
الموضوعات:
электронный ресурс
труды учёных ТПУ
дициклопентадиен
сополимеризация
метатезис
сополимеры
الوصول للمادة أونلاين:https://doi.org/10.1134/S1811238219010119
التنسيق: الكتروني فصل الكتاب
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=661170
الوصف
الملخص:Title screen
In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1134/S1811238219010119

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