Calculation of Uniform Corrosion Current Density of Iron in Hydrochloric Acid Solutions based on the Principle of Maximum Entropy Production Rate Applied to Literature Data; Protection of Metals and Physical Chemistry of Surfaces; Vol. 54, iss. 4

Calculation of Uniform Corrosion Current Density of Iron in Hydrochloric Acid Solutions based on the Principle of Maximum Entropy Production Rate Applied to Literature Data; Protection of Metals and Physical Chemistry of Surfaces; Vol. 54, iss. 4

Dades bibliogràfiques
Parent link:	Protection of Metals and Physical Chemistry of Surfaces Vol. 54, iss. 4.— 2018.— [P. 673-679]
Autor corporatiu:	Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Научно-образовательный центр Б. П. Вейнберга
Altres autors:	Bestetti M. Massimiliano, Franz S. Silvia, Hashempour M. Mazdak, Vicenzo A. Antonello
Sumari:	Title screen In this paper a new procedure for the calculation of uniform corrosion current density is presented. The procedure is based on the following criterion: corrosion current and extent of anodic and cathodic areas are such that the entropy production rate is maximum. Experimental data for the reaction Fe(s) + HCl(aq) = FeCl2(aq) + H2(g), taken from literature, are used to test the new model. A comparison between corrosion current density calculated from weight loss measurements and current density calculated from polarization curves by means of the proposed model is carried out. The proposed model provides a better agreement, between Tafel line extrapolation and gravimetric measurement, in comparison to the mixed potential theory usually adopted. AM_Agreement
Idioma:	anglès
Publicat:	2018
Matèries:	электронный ресурс труды учёных ТПУ corrosion current density uniform corrosion entropy production rate exchange current density Tafel slope коррозии плотность обменные потоки энтропия
Accés en línia:	https://doi.org/10.1134/S2070205118040160
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=661132

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