Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam; Applied Surface Science; Vol. 483

Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam; Applied Surface Science; Vol. 483

Bibliographic Details
Parent link:Applied Surface Science
Vol. 483.— 2019.— [P. 19-25]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа неразрушающего контроля и безопасности Отделение контроля и диагностики
Other Authors: Rogachev A. A., Yarmolenko M. A., Rogachev A. V., Jiang Xiaohong, Hongtao Cao, Lysenko E. N. Elena Nikolaevna, Surzhikov A. P. Anatoly Petrovich
Summary:Title screen
Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2019
Subjects:
электронный ресурс
труды учёных ТПУ
active gas phase
low-energy electron beam deposition
polyaniline-based nanocomposite coating
impedance spectroscopy
газовые фазы
нанокомпозитные покрытия
полианилин
импеданская спектрометрия
низкоэнергетические электроны
Online Access:https://doi.org/10.1016/j.apsusc.2019.03.159
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660992

Similar Items

Similar Items