Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam
| Parent link: | Applied Surface Science Vol. 483.— 2019.— [P. 19-25] |
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| Yhteisötekijä: | |
| Muut tekijät: | , , , , , , |
| Yhteenveto: | Title screen Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. Режим доступа: по договору с организацией-держателем ресурса |
| Julkaistu: |
2019
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| Aiheet: | |
| Linkit: | https://doi.org/10.1016/j.apsusc.2019.03.159 |
| Aineistotyyppi: | Elektroninen Kirjan osa |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660992 |
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| 200 | 1 | |a Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam |f A. A. Rogachev [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 34 tit.] | ||
| 330 | |a Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10?S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Applied Surface Science | ||
| 463 | |t Vol. 483 |v [P. 19-25] |d 2019 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a active gas phase | |
| 610 | 1 | |a low-energy electron beam deposition | |
| 610 | 1 | |a polyaniline-based nanocomposite coating | |
| 610 | 1 | |a impedance spectroscopy | |
| 610 | 1 | |a газовые фазы | |
| 610 | 1 | |a нанокомпозитные покрытия | |
| 610 | 1 | |a полианилин | |
| 610 | 1 | |a импеданская спектрометрия | |
| 610 | 1 | |a низкоэнергетические электроны | |
| 701 | 1 | |a Rogachev |b A. A. | |
| 701 | 1 | |a Yarmolenko |b M. A. | |
| 701 | 1 | |a Rogachev |b A. V. | |
| 701 | 0 | |a Jiang Xiaohong | |
| 701 | 0 | |a Hongtao Cao | |
| 701 | 1 | |a Lysenko |b E. N. |c Specialist in the field of electrical engineering |c Professor of Tomsk Polytechnic University, Doctor of technical sciences |f 1972- |g Elena Nikolaevna |3 (RuTPU)RU\TPU\pers\32050 |9 16097 | |
| 701 | 1 | |a Surzhikov |b A. P. |c physicist |c Professor of Tomsk Polytechnic University, doctor of physical and mathematical sciences (DSc) |f 1951- |g Anatoly Petrovich |3 (RuTPU)RU\TPU\pers\30237 |9 14617 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа неразрушающего контроля и безопасности |b Отделение контроля и диагностики |3 (RuTPU)RU\TPU\col\23584 |
| 801 | 2 | |a RU |b 63413507 |c 20191114 |g RCR | |
| 856 | 4 | |u https://doi.org/10.1016/j.apsusc.2019.03.159 | |
| 942 | |c CF | ||