Improvement of Thermal Cycling Resistance of AlxSi1−xN Coatings on Cu Substrates by Optimizing Al/Si Ratio

Detalles Bibliográficos
Parent link:Materials
Vol. 12, iss. 14.— 2019.— [2249, 12 p.]
Outros autores: Panin A. V. Alexey Viktorovich, Shugurov A. R. Artur Rubinovich, Kazachenok M. S. Marina Sergeevna, Sergeev V. P. Viktor Petrovich
Summary:Title screen
The effect of the elemental composition of AlxSi1−xN coatings deposited on Cu substrates by magnetron sputtering on their structure, mechanical properties and thermal cycling performance is studied. The coatings with Al-Si-N solid solution, two-phase (AlxSi1−xN nanocrystallites embedded in the SixNy tissue phase) and amorphous structure were obtained by varying Al/Si ratio. It is shown that polycrystalline coatings with a low Si content (Al0.88Si0.12N) are characterized by the highest thermal cycling resistance. While the coatings with a high and intermediate Si content (Al0.11Si0.89N and Al0.74Si0.26N) were subjected to cracking and spallation after the first cycle of annealing at a temperature of 1000 ◦C, delamination of the Al0.88Si0.12N coating was observed after 25 annealing cycles. The Al0.88Si0.12N coating also exhibited the best barrier performance against copper diffusion from the substrate. The effect of thermal stresses on the diffusion barrier performance of the coatings against copper diffusion is discussed.
Idioma:inglés
Publicado: 2019
Subjects:
Acceso en liña:http://earchive.tpu.ru/handle/11683/57276
https://doi.org/10.3390/ma12142249
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660974

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200 1 |a Improvement of Thermal Cycling Resistance of AlxSi1−xN Coatings on Cu Substrates by Optimizing Al/Si Ratio  |f A. V. Panin [et al.] 
203 |a Text  |c electronic 
300 |a Title screen 
320 |a [References: 53 tit.] 
330 |a The effect of the elemental composition of AlxSi1−xN coatings deposited on Cu substrates by magnetron sputtering on their structure, mechanical properties and thermal cycling performance is studied. The coatings with Al-Si-N solid solution, two-phase (AlxSi1−xN nanocrystallites embedded in the SixNy tissue phase) and amorphous structure were obtained by varying Al/Si ratio. It is shown that polycrystalline coatings with a low Si content (Al0.88Si0.12N) are characterized by the highest thermal cycling resistance. While the coatings with a high and intermediate Si content (Al0.11Si0.89N and Al0.74Si0.26N) were subjected to cracking and spallation after the first cycle of annealing at a temperature of 1000 ◦C, delamination of the Al0.88Si0.12N coating was observed after 25 annealing cycles. The Al0.88Si0.12N coating also exhibited the best barrier performance against copper diffusion from the substrate. The effect of thermal stresses on the diffusion barrier performance of the coatings against copper diffusion is discussed. 
461 |t Materials 
463 |t Vol. 12, iss. 14  |v [2249, 12 p.]  |d 2019 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a copper 
610 1 |a magnetron sputtering 
610 1 |a thermal cycling performance 
610 1 |a scanning electron microscopy 
610 1 |a cracking 
610 1 |a медь 
610 1 |a магнетронные покрытия 
701 1 |a Panin  |b A. V.  |c physicist  |c Professor of Tomsk Polytechnic University, doctor of physical and mathematical Sciences  |f 1971-  |g Alexey Viktorovich  |3 (RuTPU)RU\TPU\pers\34630  |9 17992 
701 1 |a Shugurov  |b A. R.  |c Specialist in the field of material science  |c Professor of Tomsk Polytechnic University, Doctor of Physical and Mathematical Sciences  |f 1967-  |g Artur Rubinovich  |y Tomsk  |9 22641 
701 1 |a Kazachenok  |b M. S.  |g Marina Sergeevna 
701 1 |a Sergeev  |b V. P.  |c specialist in the field of materials science  |c Professor of Tomsk Polytechnic University, doctor of technical Sciences  |f 1949-  |g Viktor Petrovich  |9 16615 
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