First high–resolution analysis of the 2?1(A1) and interacting states of 72GeH4 and 73GeH4; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 236
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 236.— 2019.— [106593, 10 p.] |
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| Korporativna značnica: | |
| Drugi avtorji: | , , , , , , , , , |
| Izvleček: | Title screen The spectra of germane 72GeH4 and 73GeH4 enriched up to 99.9 % were recorded with high resolution (0.003 cm−1) at different pressures with the Bruker IFS 125HR Fourier transform spectrometer (Nizhny Novgorod, Russia). The region of 4020-4260 cm−1, where the 2ν1(A1) and ν1+ν3(F2) bands are located, was theoretically analyzed. The 2025 and 1774 transitions with Jmax=21 were assigned to these bands of the 72GeH4 and 73GeH4 species. Rotational, centrifugal distortion, tetrahedral splitting, and interaction parameters of the (2000, A1) and (1010, F2) vibrational states were determined from the fit of experimental line positions of both isotopologues. The obtained sets of 13/13 fitted parameters reproduce the initial 2025/1774 experimental line positions with a drms=2.9×10−4 cm−1 and drms=2.7×10−4 cm−1 (for 72GeH4 and 73GeH4, respectively). Режим доступа: по договору с организацией-держателем ресурса |
| Jezik: | angleščina |
| Izdano: |
2019
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| Teme: | |
| Online dostop: | https://doi.org/10.1016/j.jqsrt.2019.106593 |
| Format: | Elektronski Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660774 |
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| 200 | 1 | |a First high–resolution analysis of the 2?1(A1) and interacting states of 72GeH4 and 73GeH4 |f O. N. Ulenekov (Ulenikov) [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 80 tit.] | ||
| 330 | |a The spectra of germane 72GeH4 and 73GeH4 enriched up to 99.9 % were recorded with high resolution (0.003 cm−1) at different pressures with the Bruker IFS 125HR Fourier transform spectrometer (Nizhny Novgorod, Russia). The region of 4020-4260 cm−1, where the 2ν1(A1) and ν1+ν3(F2) bands are located, was theoretically analyzed. The 2025 and 1774 transitions with Jmax=21 were assigned to these bands of the 72GeH4 and 73GeH4 species. Rotational, centrifugal distortion, tetrahedral splitting, and interaction parameters of the (2000, A1) and (1010, F2) vibrational states were determined from the fit of experimental line positions of both isotopologues. The obtained sets of 13/13 fitted parameters reproduce the initial 2025/1774 experimental line positions with a drms=2.9×10−4 cm−1 and drms=2.7×10−4 cm−1 (for 72GeH4 and 73GeH4, respectively). | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 236 |v [106593, 10 p.] |d 2019 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a the 2v1/v1+v3 interacting states of GeH4 | |
| 610 | 1 | |a resonance interactions in spherical top molecules | |
| 610 | 1 | |a determination of spectroscopic parameters | |
| 610 | 1 | |a резонансные взаимодействия | |
| 610 | 1 | |a сферические модели | |
| 610 | 1 | |a спектроскопические параметры | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Raspopova |b N. I. |c physicist |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences |f 1990- |g Natalya Ivanovna |3 (RuTPU)RU\TPU\pers\34080 |9 17636 | |
| 701 | 1 | |a Koshelev |b M. A. |g Maksim Aleksandrovich | |
| 701 | 1 | |a Velmuzhova |b I. A. | |
| 701 | 1 | |a Sennikov |b P. G. |g Petr Gennadjevich | |
| 701 | 1 | |a Bulanov |b A. D. |g Andrey Dmitrievich | |
| 701 | 1 | |a Kuznetsov |b A. V. |c Physicist |c Engineer of Tomsk Polytechnic University |f 1994- |g Alexey Valerevich |3 (RuTPU)RU\TPU\pers\44420 | |
| 701 | 1 | |a Leroy |b K. A. |g Klod Andre | |
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