Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers

Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers

Bibliographic Details
Parent link:	Molecules Vol. 24, iss. 15.— 2019.— [2717, 12 p.]
Corporate Author:	Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-образовательный центр Н. М. Кижнера
Other Authors:	Pavlov D. I. Dmitry Igorevich, Sukhikh T. S. Taisiya Sergeevna, Filatov E. Yu. Evgeny Yurjevich, Potapov A. S. Andrey Sergeevich
Summary:	Title screen For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]•DMF•0.3H2O, [Cu(trzadc)2(MeOH)]•MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3– (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]•MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.
Published:	2019
Subjects:	труды учёных ТПУ электронный ресурс adamantane carboxylate ligands chain structures heterocyclic ligands metal-organic frameworks адамантан карбоксилаты цепные схемы металлоорганические соединения
Online Access:	https://doi.org/10.3390/molecules24152717
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660583

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