Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers
| Parent link: | Molecules Vol. 24, iss. 15.— 2019.— [2717, 12 p.] |
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| Corporate Author: | |
| Other Authors: | , , , |
| Summary: | Title screen For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]•DMF•0.3H2O, [Cu(trzadc)2(MeOH)]•MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3– (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]•MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction. |
| Published: |
2019
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| Subjects: | |
| Online Access: | https://doi.org/10.3390/molecules24152717 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660583 |
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| 200 | 1 | |a Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers |f D. I. Pavlov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 48 tit.] | ||
| 330 | |a For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]•DMF•0.3H2O, [Cu(trzadc)2(MeOH)]•MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3– (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]•MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction. | ||
| 461 | |t Molecules | ||
| 463 | |t Vol. 24, iss. 15 |v [2717, 12 p.] |d 2019 | ||
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a adamantane | |
| 610 | 1 | |a carboxylate ligands | |
| 610 | 1 | |a chain structures | |
| 610 | 1 | |a heterocyclic ligands | |
| 610 | 1 | |a metal-organic frameworks | |
| 610 | 1 | |a адамантан | |
| 610 | 1 | |a карбоксилаты | |
| 610 | 1 | |a цепные схемы | |
| 610 | 1 | |a металлоорганические соединения | |
| 701 | 1 | |a Pavlov |b D. I. |g Dmitry Igorevich | |
| 701 | 1 | |a Sukhikh |b T. S. |g Taisiya Sergeevna | |
| 701 | 1 | |a Filatov |b E. Yu. |g Evgeny Yurjevich | |
| 701 | 1 | |a Potapov |b A. S. |c Chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1981- |g Andrey Sergeevich |3 (RuTPU)RU\TPU\pers\33909 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа новых производственных технологий |b Научно-образовательный центр Н. М. Кижнера |3 (RuTPU)RU\TPU\col\23556 |
| 801 | 2 | |a RU |b 63413507 |c 20190808 |g RCR | |
| 856 | 4 | 0 | |u https://doi.org/10.3390/molecules24152717 |
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