First detection of the rare hydrogen sulfide isotopologue: The pure rotational and ?2 bands of HD33S
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 232.— 2019.— [P. 108-115] |
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| Other Authors: | , , , , |
| Summary: | Title screen The high–resolution infrared spectrum of the HDS isotopologue was recorded and analyzed in the region of the ?2 fundamental band region (700–1400?cm) with a Bruker IFS 125HR Fourier transform infrared spectrometer (Zurich prototype ZP2001). Among the lines of the ?2 band of the HD32S and HD34S molecules, 801 transitions of HD33S were found in the spectrum and assigned for the first time (Jmax = 19 and = 12). Also for the first time, rotational energies of the ground vibrational state were determined from the 87 ground state combination differences obtained from the experimental data. Fits of parameters of the Watson hamiltonian with both ground state combination differences and ro–vibrational energy values (line positions) of the (010) vibrational state were made. Parameters of the effective dipole moments of the pure rotational transitions and of the ?2 band are obtained. Line lists (line positions and line strengths) of the pure rotational transitions and transitions belonging to the ?2 band are generated which can be useful for astrophysical and planetological applications. Режим доступа: по договору с организацией-держателем ресурса |
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2019
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| Online Access: | https://doi.org/10.1016/j.jqsrt.2019.05.004 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660571 |
| Summary: | Title screen The high–resolution infrared spectrum of the HDS isotopologue was recorded and analyzed in the region of the ?2 fundamental band region (700–1400?cm) with a Bruker IFS 125HR Fourier transform infrared spectrometer (Zurich prototype ZP2001). Among the lines of the ?2 band of the HD32S and HD34S molecules, 801 transitions of HD33S were found in the spectrum and assigned for the first time (Jmax = 19 and = 12). Also for the first time, rotational energies of the ground vibrational state were determined from the 87 ground state combination differences obtained from the experimental data. Fits of parameters of the Watson hamiltonian with both ground state combination differences and ro–vibrational energy values (line positions) of the (010) vibrational state were made. Parameters of the effective dipole moments of the pure rotational transitions and of the ?2 band are obtained. Line lists (line positions and line strengths) of the pure rotational transitions and transitions belonging to the ?2 band are generated which can be useful for astrophysical and planetological applications. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1016/j.jqsrt.2019.05.004 |