Sorption and desorption of BrF3 on NaF: Studies on thermodynamics and kinetics; Journal of Fluorine Chemistry; Vol. 221

Sorption and desorption of BrF3 on NaF: Studies on thermodynamics and kinetics; Journal of Fluorine Chemistry; Vol. 221

Bibliographic Details
Parent link:Journal of Fluorine Chemistry
Vol. 221.— 2019.— [P. 25-33]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение ядерно-топливного цикла
Other Authors: Zherin (Gerin) I. I. Ivan Ignatyevich, Rudnikov A. I., Ostvald R. V. Roman Vyacheslavovich, Sobolev V. I., Amelina G. N. Galina Nikolayevna
Summary:Title screen
Temperature dependence of bromine trifluoride vapor pressure over its adduct with sodium fluoride has been determined; the adduct normal dissociation temperature has been determined. Kinetics of sorption and desorption processes in BrF3(gas)–NaF(solid) system have been studied.The equation was proposed to illustrate the link between forward reaction rate (??) described by Arrhenius equation and experimental value (Ki): Ki= K?· (Pa/Peq)m, where Ki – observed reaction rate constant, Ka – forward reaction rate constant described by Arrhenius equation; Pa – partial pressure of BrF3; Peq – equilibrium pressure of BrF3 above BrF3·3NaF; m – factor characterizing the interaction area of BrF3 with NaF. The application of this equation makes possible to determine the true reaction rate values and reaction activation energy in chemisorption terms; it also helps to calculate the degree BrF3 sorption on NaF reaction at different temperatures and adsorbate pressures. The possibility of sorption-desorption separation of bromine trifluoride – uranium hexafluoride – iodine pentafluoride system with use of sodium fluoride was shown.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2019
Subjects:
электронный ресурс
труды учёных ТПУ
Uranium hexafluoride
Bromine trifluoride
Iodine pentafluoride
Sodium fluoride
Sorption
Desorption
гексафторид урана
трифторид брома
пентафторид йода
фторид натрия
сорбция
десорбция
Online Access:https://doi.org/10.1016/j.jfluchem.2019.03.003
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660359

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