Fully-sulfonated hydrated UiO66 as efficient catalyst for ethyl levulinate production by esterification; Catalysis Communications; Vol. 117

Fully-sulfonated hydrated UiO66 as efficient catalyst for ethyl levulinate production by esterification; Catalysis Communications; Vol. 117

Detalhes bibliográficos
Parent link:Catalysis Communications
Vol. 117.— 2018.— [P. 33-37]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Outros Autores: Desidery L. Luca, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhuiykov S. Serge, Verpoort F. V. K. Frensis Valter Kornelius
Resumo:Title screen
Partially and fully sulfonated UiO66 derivatives, along with the non-functionalized MOF, were synthetized by one-step solvothermal synthesis. Structural, acid and porous properties were investigated before and after dehydration and thermal activation processes. Hydrated, dehydrated and thermally activated materials were screened as a heterogeneous catalyst towards the esterification of levulinic acid with ethanol in order to determine the effects of the exposed acid functionalities amount and hydration. The hydrated fully sulfonated UiO66 presented the highest activity and resulted to be more efficient than commercial Amberlyst 15. It also demonstrated high stability and recyclability in consecutive reaction runs.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2018
Assuntos:
электронный ресурс
труды учёных ТПУ
MOF
UiO66
UiO66-SO3H
activation process
esterification
ethyl levulinate
активация
Acesso em linha:https://doi.org/10.1016/j.catcom.2018.08.020
Formato: MixedMaterials Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660156

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