Synthesis and characterization of chitosan-based waterborne polyurethane for textile finishes; Carbohydrate Polymers; Vol. 200

Podrobná bibliografie
Parent link:Carbohydrate Polymers
Vol. 200.— 2018.— [P. 54-62]
Korporativní autor: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Další autoři: Naz Farah, Zuber Mohammad, Zia Khalid Mehmood, Salman Mahwish, Chakraborty Jeet, Nath Ipsita, Verpoort F. V. K. Frensis Valter Kornelius
Shrnutí:Title screen
Chitosan has gained an increased interest of researchers due to its nontoxic, biodegradable, biocompatible and renewable properties as well as its antimicrobial activity. In this work, a series of chitosan-based waterborne polyurethane (CS-WPU) emulsions were synthesized. The synthesis was accomplished by using a two-step emulsion polymerization process. The pre-polymer was prepared using hexamethylene diisocyanate (HDI) and polyethylene glycol (PEG; MW?=?6?kDa). Afterwards, the chain extension step was performed by using different mole ratios of chitosan. Moreover, the effect of chitosan on physicochemical properties of the emulsion was studied. To evaluate textile performances such as tear strength, tensile strength and pilling, the CS-WPU emulsion was applied on different plain weave polyester cotton dyed and printed fabrics by using pad-dry cure techniques. The antimicrobial activity of the treated and untreated fabrics was also evaluated via the agar diffusion method. The results displayed that incorporation of chitosan has prominent effects on tensile tear strength, tear strength and antimicrobial activity of polyester cotton dyed and printed fabrics. Moreover, antimicrobial activity was considerably enhanced as the mole ratio of the chitosan was increased. The results emphasize that CS-WPU based on HDI exhibits a better performance as compared to IPDI.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2018
Témata:
On-line přístup:https://doi.org/10.1016/j.carbpol.2018.07.076
Médium: MixedMaterials Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660131

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330 |a Chitosan has gained an increased interest of researchers due to its nontoxic, biodegradable, biocompatible and renewable properties as well as its antimicrobial activity. In this work, a series of chitosan-based waterborne polyurethane (CS-WPU) emulsions were synthesized. The synthesis was accomplished by using a two-step emulsion polymerization process. The pre-polymer was prepared using hexamethylene diisocyanate (HDI) and polyethylene glycol (PEG; MW?=?6?kDa). Afterwards, the chain extension step was performed by using different mole ratios of chitosan. Moreover, the effect of chitosan on physicochemical properties of the emulsion was studied. To evaluate textile performances such as tear strength, tensile strength and pilling, the CS-WPU emulsion was applied on different plain weave polyester cotton dyed and printed fabrics by using pad-dry cure techniques. The antimicrobial activity of the treated and untreated fabrics was also evaluated via the agar diffusion method. The results displayed that incorporation of chitosan has prominent effects on tensile tear strength, tear strength and antimicrobial activity of polyester cotton dyed and printed fabrics. Moreover, antimicrobial activity was considerably enhanced as the mole ratio of the chitosan was increased. The results emphasize that CS-WPU based on HDI exhibits a better performance as compared to IPDI. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Carbohydrate Polymers 
463 |t Vol. 200  |v [P. 54-62]  |d 2018 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a chitosan-based waterborne polyurethane 
610 1 |a tear strength 
610 1 |a tensile strength 
610 1 |a antimicrobial activity 
610 1 |a pilling 
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701 0 |a Chakraborty Jeet 
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