High resolution analysis of the FTIR spectra of trifluoroamine NF3

מידע ביבליוגרפי
Parent link:Journal of Molecular Spectroscopy
Vol. 348.— 2018.— [P. 87-102]
מחבר תאגידי: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
מחברים אחרים: Bolotova I. B. Irina Batorovna, Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Bekhtereva E. S. Elena Sergeevna, Albert S. Sieghard, Hollenstein H. A. Hans, Quack M. Martin, Peter T., Seyfang G. Georg, Wokaun A. Alexander
סיכום:Title screen
We report high resolution Fourier Transform Infrared (FTIR) spectra of nitrogen trifluoride (trifluoroamine, NF3) measured with the Zürich Bruker prototype spectrometer (ZP 2001) and the SLS THz/FTIR setup (2009 prototype) in the range 20-3000 cm-1 at temperatures between 80 and 120 K using a collisional cooling cell designed with White cell multipath reflection optics and at room temperature (296 K). Except in the far-infrared with instrument limited resolution (Δν̃FWHM = 0.0008 cm-1) many of the spectra are nearly Doppler limited. Rovibrational transitions were assigned to 13 different vibrational bands and were used then in the fitting procedure. We re-investigated the bands 2ν4,ν1,ν2+ν4,ν1+ν4, 2ν3 and ν1+ν3, which had been studied before, and we have analyzed the ν2+ν3, 2ν1,ν1+ν2+ν4,ν1+ν2+ν3,ν2+2ν3,3ν3,ν1+2ν3 bands for the first time. All our analyses refer to the isotopomer 14NF3.
Режим доступа: по договору с организацией-держателем ресурса
שפה:אנגלית
יצא לאור: 2018
נושאים:
גישה מקוונת:https://doi.org/10.1016/j.jms.2018.04.004
פורמט: אלקטרוני Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=660096

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