Reflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations; Journal of Solution Chemistry; Vol. 48, iss. 3

Reflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations; Journal of Solution Chemistry; Vol. 48, iss. 3

Bibliographic Details
Parent link:Journal of Solution Chemistry
Vol. 48, iss. 3.— 2019.— [P. 354-366]
Main Author: Tereshchenko A. G. Anatoly Georgievich
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-производственная лаборатория "Чистая вода"
Summary:Title screen
This review article considers factors that affect the duration and accuracy of isopiestic investigations, analyzes data from published papers, and provides the author’s critical opinion. The interrelation between the mass of the transported water vapor during isothermal distillation and the driving force behind the process for solutions of various concentrations is studied. The significance of the effects of removal of air, agitating in the liquid and gas phases, materials of the isopiestic cups on the duration of the isopiestic process is also analyzed. Attention is paid to the fact that if an initial reagent that contains 0.99 mol fraction main component is used without prior purification, then the accuracy of this isopiestic investigation is questionable even in the second figure of the isopiestic measurement result.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2019
Subjects:
электронный ресурс
труды учёных ТПУ
isopiestic method
rate-limiting step
accuracy of results
experiment duration
review
изопиестические методы
точность
результаты
продолжительность
эксперименты
обзор
Online Access:https://doi.org/10.1007/s10953-019-00849-3
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659975

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