Reflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations; Journal of Solution Chemistry; Vol. 48, iss. 3
| Parent link: | Journal of Solution Chemistry Vol. 48, iss. 3.— 2019.— [P. 354-366] |
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| 第一著者: | |
| 団体著者: | |
| 要約: | Title screen This review article considers factors that affect the duration and accuracy of isopiestic investigations, analyzes data from published papers, and provides the author’s critical opinion. The interrelation between the mass of the transported water vapor during isothermal distillation and the driving force behind the process for solutions of various concentrations is studied. The significance of the effects of removal of air, agitating in the liquid and gas phases, materials of the isopiestic cups on the duration of the isopiestic process is also analyzed. Attention is paid to the fact that if an initial reagent that contains 0.99 mol fraction main component is used without prior purification, then the accuracy of this isopiestic investigation is questionable even in the second figure of the isopiestic measurement result. Режим доступа: по договору с организацией-держателем ресурса |
| 言語: | 英語 |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://doi.org/10.1007/s10953-019-00849-3 |
| フォーマット: | 電子媒体 図書の章 |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659975 |
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| 200 | 1 | |a Reflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations |f A. G. Tereshchenko | |
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| 300 | |a Title screen | ||
| 320 | |a [References: 49 tit.] | ||
| 330 | |a This review article considers factors that affect the duration and accuracy of isopiestic investigations, analyzes data from published papers, and provides the author’s critical opinion. The interrelation between the mass of the transported water vapor during isothermal distillation and the driving force behind the process for solutions of various concentrations is studied. The significance of the effects of removal of air, agitating in the liquid and gas phases, materials of the isopiestic cups on the duration of the isopiestic process is also analyzed. Attention is paid to the fact that if an initial reagent that contains 0.99 mol fraction main component is used without prior purification, then the accuracy of this isopiestic investigation is questionable even in the second figure of the isopiestic measurement result. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Solution Chemistry | ||
| 463 | |t Vol. 48, iss. 3 |v [P. 354-366] |d 2019 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a isopiestic method | |
| 610 | 1 | |a rate-limiting step | |
| 610 | 1 | |a accuracy of results | |
| 610 | 1 | |a experiment duration | |
| 610 | 1 | |a review | |
| 610 | 1 | |a изопиестические методы | |
| 610 | 1 | |a точность | |
| 610 | 1 | |a результаты | |
| 610 | 1 | |a продолжительность | |
| 610 | 1 | |a эксперименты | |
| 610 | 1 | |a обзор | |
| 700 | 1 | |a Tereshchenko |b A. G. |c Chemical Engineer |c Head of the laboratory of Tomsk Polytechnic University, Candidate of technical science |f 1946- |g Anatoly Georgievich |3 (RuTPU)RU\TPU\pers\31487 |9 15648 | |
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