Synthesis of Five-Membered Iodine–Nitrogen Heterocycles from Benzimidazole-Based Iodonium Salts; Journal of Organic Chemistry (JOC); Vol. 83, iss. 19

Synthesis of Five-Membered Iodine–Nitrogen Heterocycles from Benzimidazole-Based Iodonium Salts; Journal of Organic Chemistry (JOC); Vol. 83, iss. 19

Dades bibliogràfiques
Parent link:Journal of Organic Chemistry (JOC)
Vol. 83, iss. 19.— 2018.— [P. 12056–12070]
Autor corporatiu: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Altres autors: Vlasenko Yu. A. Yuliya Aleksandrovna, Postnikov P. S. Pavel Sergeevich, Trusova M. E. Marina Evgenievna, Shafir A. Alexandr, Zhdankin V. V. Viktor Vladimirovich, Yoshimura A. Akira, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich)
Sumari:Title screen
Pseudocyclic 2-benzimidazolyl-substituted diaryliodonium salts were obtained by the reaction of the corresponding [hydroxy(tosyloxy)iodo]arenes with arenes in the presence of trifluoromethanesulfonic acid. X-ray structural analysis of these iodonium salts confirmed their pseudocyclic structure with a short (2.57–2.58 A) noncovalent I···N interaction. Treatment of 2-benzimidazolyl-substituted diaryliodonium triflates with a base afforded novel five-membered iodine–nitrogen heterocycles.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:anglès
Publicat: 2018
Matèries:
электронный ресурс
труды учёных ТПУ
синто
пятичленные гетероциклы
иодониевые соли
бензимидазолы
Accés en línia:https://doi.org/10.1021/acs.joc.8b01995
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659786
Descripció
Sumari:Title screen
Pseudocyclic 2-benzimidazolyl-substituted diaryliodonium salts were obtained by the reaction of the corresponding [hydroxy(tosyloxy)iodo]arenes with arenes in the presence of trifluoromethanesulfonic acid. X-ray structural analysis of these iodonium salts confirmed their pseudocyclic structure with a short (2.57–2.58 A) noncovalent I···N interaction. Treatment of 2-benzimidazolyl-substituted diaryliodonium triflates with a base afforded novel five-membered iodine–nitrogen heterocycles.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1021/acs.joc.8b01995

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