Synthesis of Five-Membered Iodine–Nitrogen Heterocycles from Benzimidazole-Based Iodonium Salts; Journal of Organic Chemistry (JOC); Vol. 83, iss. 19
| Parent link: | Journal of Organic Chemistry (JOC) Vol. 83, iss. 19.— 2018.— [P. 12056–12070] |
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| 企業作者: | |
| 其他作者: | , , , , , , |
| 總結: | Title screen Pseudocyclic 2-benzimidazolyl-substituted diaryliodonium salts were obtained by the reaction of the corresponding [hydroxy(tosyloxy)iodo]arenes with arenes in the presence of trifluoromethanesulfonic acid. X-ray structural analysis of these iodonium salts confirmed their pseudocyclic structure with a short (2.57–2.58 A) noncovalent I···N interaction. Treatment of 2-benzimidazolyl-substituted diaryliodonium triflates with a base afforded novel five-membered iodine–nitrogen heterocycles. Режим доступа: по договору с организацией-держателем ресурса |
| 語言: | 英语 |
| 出版: |
2018
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| 主題: | |
| 在線閱讀: | https://doi.org/10.1021/acs.joc.8b01995 |
| 格式: | 電子 Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659786 |
| 總結: | Title screen Pseudocyclic 2-benzimidazolyl-substituted diaryliodonium salts were obtained by the reaction of the corresponding [hydroxy(tosyloxy)iodo]arenes with arenes in the presence of trifluoromethanesulfonic acid. X-ray structural analysis of these iodonium salts confirmed their pseudocyclic structure with a short (2.57–2.58 A) noncovalent I···N interaction. Treatment of 2-benzimidazolyl-substituted diaryliodonium triflates with a base afforded novel five-membered iodine–nitrogen heterocycles. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1021/acs.joc.8b01995 |