Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle; Beilstein Journal of Organic Chemistry; Vol. 14

গ্রন্থ-পঞ্জীর বিবরন
Parent link:Beilstein Journal of Organic Chemistry
Vol. 14.— 2018.— [P. 1016-1020]
সংস্থা লেখক: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
অন্যান্য লেখক: Yoshimura A. Akira, Shea M. T. Michael T., Makitalo C. L. Cody L., Jarvi M. E. Melissa E., Rohde G. T. Gregory T., Saito A. Akio, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich
সংক্ষিপ্ত:Title screen
A new bicyclic organohypervalent iodine heterocycle derivative of benziodazole was prepared by oxidation of 2-iodo-N,N’-diisopropylisophthalamide with m-chloroperoxybenzoic acid under mild conditions. Single crystal X-ray crystallography of this compound revealed a five-membered bis-heterocyclic structure with two covalent bonds between the iodine atom and the nitrogen atoms. This novel benziodazole is a very stable compound with good solubility in common organic solvents. This compound can be used as an efficient reagent for oxidatively assisted coupling of carboxylic acids with alcohols or amines to afford the corresponding esters or amides in moderate yields.
ভাষা:ইংরেজি
প্রকাশিত: 2018
বিষয়গুলি:
অনলাইন ব্যবহার করুন:http://dx.doi.org/10.3762/bjoc.14.87
বিন্যাস: বৈদ্যুতিক গ্রন্থের অধ্যায়
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659710

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