Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle; Beilstein Journal of Organic Chemistry; Vol. 14
| Parent link: | Beilstein Journal of Organic Chemistry Vol. 14.— 2018.— [P. 1016-1020] |
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| Autor corporatiu: | |
| Altres autors: | , , , , , , , |
| Sumari: | Title screen A new bicyclic organohypervalent iodine heterocycle derivative of benziodazole was prepared by oxidation of 2-iodo-N,N’-diisopropylisophthalamide with m-chloroperoxybenzoic acid under mild conditions. Single crystal X-ray crystallography of this compound revealed a five-membered bis-heterocyclic structure with two covalent bonds between the iodine atom and the nitrogen atoms. This novel benziodazole is a very stable compound with good solubility in common organic solvents. This compound can be used as an efficient reagent for oxidatively assisted coupling of carboxylic acids with alcohols or amines to afford the corresponding esters or amides in moderate yields. |
| Idioma: | anglès |
| Publicat: |
2018
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| Matèries: | |
| Accés en línia: | http://dx.doi.org/10.3762/bjoc.14.87 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659710 |
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| 200 | 1 | |a Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle |f A. Yoshimura, M. T. Shea , C. L. Makitalo [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 38 tit.] | ||
| 330 | |a A new bicyclic organohypervalent iodine heterocycle derivative of benziodazole was prepared by oxidation of 2-iodo-N,N’-diisopropylisophthalamide with m-chloroperoxybenzoic acid under mild conditions. Single crystal X-ray crystallography of this compound revealed a five-membered bis-heterocyclic structure with two covalent bonds between the iodine atom and the nitrogen atoms. This novel benziodazole is a very stable compound with good solubility in common organic solvents. This compound can be used as an efficient reagent for oxidatively assisted coupling of carboxylic acids with alcohols or amines to afford the corresponding esters or amides in moderate yields. | ||
| 461 | |t Beilstein Journal of Organic Chemistry | ||
| 463 | |t Vol. 14 |v [P. 1016-1020] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a гипервалентный йод | |
| 610 | 1 | |a йод | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a benziodazole | |
| 610 | 1 | |a biheterocycles | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a iodine | |
| 610 | 1 | |a oxidatively assisted esterification | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 | |
| 701 | 1 | |a Shea |b M. T. |g Michael T. | |
| 701 | 1 | |a Makitalo |b C. L. |g Cody L. | |
| 701 | 1 | |a Jarvi |b M. E. |g Melissa E. | |
| 701 | 1 | |a Rohde |b G. T. |g Gregory T. | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Zhdankin |b V. V. |c химик |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |3 (RuTPU)RU\TPU\pers\35758 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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