Investigation of the Fine Energy Structure of the (0100, E) and (0001, F2) Vibrational States of the 73GeH4 Molecule; Russian Physics Journal; Vol. 61, iss. 7

Investigation of the Fine Energy Structure of the (0100, E) and (0001, F2) Vibrational States of the 73GeH4 Molecule; Russian Physics Journal; Vol. 61, iss. 7

Détails bibliographiques
Parent link:Russian Physics Journal
Vol. 61, iss. 7.— 2018.— [P. 1281–1287]
Auteur principal: Raspopova N. I. Natalya Ivanovna
Collectivités auteurs: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов, Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение экспериментальной физики
Autres auteurs: Sklyarova E. A. Elena Aleksandrovna, Sennikov P. G. Petr Gennadjevich
Résumé:Title screen
The IR spectrum of the 73GeH4 molecule is recorded with a Bruker IFS 125HR high-resolution Fourier spectrometer in the range 650–1100 cm–1 and then analyzed; 1127 transitions with Jmax = 19 are assigned to the ?4 and ?2 bands of the 73GeH4 molecule. The rotational and centrifugal parameters of tetrahedral splitting and the Coriolis interaction parameters for the (0100, E) ground and (0001, F2) vibrational states are determined by varying positions of the experimental lines. The obtained set of the spectroscopic parameters reproduces the initial experimental data with the accuracy close to the experimental one.
Режим доступа: по договору с организацией-держателем ресурса
Langue:anglais
Publié: 2018
Sujets:
электронный ресурс
труды учёных ТПУ
IR spectroscopy
rovibrational spectrum
spherical top molecules
tetrahedral splittings
spectroscopic parameters
ИК-спектроскопия
колебательные спектры
волчок
параметры
Accès en ligne:https://doi.org/10.1007/s11182-018-1530-3
Format: Électronique Chapitre de livre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=659270
Description
Résumé:Title screen
The IR spectrum of the 73GeH4 molecule is recorded with a Bruker IFS 125HR high-resolution Fourier spectrometer in the range 650–1100 cm–1 and then analyzed; 1127 transitions with Jmax = 19 are assigned to the ?4 and ?2 bands of the 73GeH4 molecule. The rotational and centrifugal parameters of tetrahedral splitting and the Coriolis interaction parameters for the (0100, E) ground and (0001, F2) vibrational states are determined by varying positions of the experimental lines. The obtained set of the spectroscopic parameters reproduces the initial experimental data with the accuracy close to the experimental one.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1007/s11182-018-1530-3

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