Determining the Parameters of the Effective Rovibrational Hamiltonian of the ν7+ν8 Band of the Ethylene-1-13C Molecule; Russian Physics Journal; Vol. 61, iss. 2

Dettagli Bibliografici
Parent link:Russian Physics Journal
Vol. 61, iss. 2.— 2018.— [P. 299-303]
Autore principale: Aslapovskaya Yu. S. Yuliya Sergeevna
Ente Autore: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Riassunto:Title screen
The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm-1 with a resolution of 0.0025 cm-1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2018
Soggetti:
Accesso online:https://doi.org/10.1007/s11182-018-1401-y
Natura: MixedMaterials Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=658853

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330 |a The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm-1 with a resolution of 0.0025 cm-1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one. 
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