Iodonium Salts as Benzyne Precursors
| Parent link: | Chemistry - A European Journal Vol. 24, iss. 57.— 2018.— [P. 15156-15166] |
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| Main Author: | |
| Corporate Author: | |
| Other Authors: | , |
| Summary: | Title screen Reactions involving benzyne and aryne intermediates have found widespread application in organic synthesis. Various benzyne precursors and benzyne generating procedures are known. Recently, methods of benzyne generation from diaryliodonium salts and related hypervalent iodine compounds have received considerable attention. These methods are characterized by mild reaction conditions and applicability in a broad range of chemical transformations. The present minireview is focused on the preparation and reactivity of hypervalent iodine based benzyne precursors. Furthermore, recent developments in their synthetic application are discussed. Режим доступа: по договору с организацией-держателем ресурса |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://doi.org/10.1002/chem.201802111 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=658608 |
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| 200 | 1 | |a Iodonium Salts as Benzyne Precursors |f A. Yoshimura, A. Saito, V. V. Zhdankin | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 15165-15166 (113 tit.)] | ||
| 330 | |a Reactions involving benzyne and aryne intermediates have found widespread application in organic synthesis. Various benzyne precursors and benzyne generating procedures are known. Recently, methods of benzyne generation from diaryliodonium salts and related hypervalent iodine compounds have received considerable attention. These methods are characterized by mild reaction conditions and applicability in a broad range of chemical transformations. The present minireview is focused on the preparation and reactivity of hypervalent iodine based benzyne precursors. Furthermore, recent developments in their synthetic application are discussed. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 1 | |t Chemistry - A European Journal | |
| 463 | 1 | |t Vol. 24, iss. 57 |v [P. 15156-15166] |d 2018 | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a arynes | |
| 610 | 1 | |a benzyne precursors | |
| 610 | 1 | |a cycloaddition | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a iodonium | |
| 610 | 1 | |a циклоприсоединение | |
| 610 | 1 | |a гипервалентный йод | |
| 700 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 | |
| 701 | 1 | |a Saito |b A. |g Akio | |
| 701 | 1 | |a Zhdankin |b V. V. |c химик |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |3 (RuTPU)RU\TPU\pers\35758 | |
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