Selective and adsorptive removal of anionic dyes and CO2 with azolium-based metal-organic frameworks; Journal of Colloid and Interface Science; Vol. 519
| Parent link: | Journal of Colloid and Interface Science Vol. 519.— 2018.— [P. 214-223] |
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| Corporate Author: | |
| Other Authors: | , , , , , , |
| Summary: | Title screen The positively charged azolium moieties make imidazolium linker an ideal linker for the construction of cationic metal-organic frameworks because the ligand induces cationic environments in the frameworks. Therefore, we employed two imidazolium ligands, 1,3-bis(4-carboxyphenyl)imidazolium chloride (H2L+ Cl) and 1,3-bis(3,5-dicarboxyphenyl)imidazolium chloride (H4L+ Cl), to synthesize two nickel azolium-based MOFs, 1 and 2. The as-synthesis MOFs were characterized by PXRD, TGA, FE-SEM, HRTEM, FTIR and BET measurements. By applying 1 and 2 in liquid phase adsorption of charged molecules of dyes, they successfully exhibit remarkable efficiency for adsorptive removal of anionic dyes, Methyl orange (MO), Congo red (CR), and Orange II sodium salt (OS), from aqueous solution. The framework proves efficient in photocatalytic degradation of anionic dye. Furthermore, in the gaseous phase adsorption, 1 and 2 selectively adsorb CO2 over CH4 due to the higher quadrupole moment of CO2. Overall, the results show that azolium-based MOFs have potential applications for adsorptive removal of charged organic contaminants from both aqueous and gaseous environment. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://doi.org/10.1016/j.jcis.2018.02.003 |
| Format: | MixedMaterials Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=657869 |
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| 200 | 1 | |a Selective and adsorptive removal of anionic dyes and CO2 with azolium-based metal-organic frameworks |f I. E. Chizoba, Md. Ali Asraf, Xiao Li [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 222-223 (53 tit.)] | ||
| 330 | |a The positively charged azolium moieties make imidazolium linker an ideal linker for the construction of cationic metal-organic frameworks because the ligand induces cationic environments in the frameworks. Therefore, we employed two imidazolium ligands, 1,3-bis(4-carboxyphenyl)imidazolium chloride (H2L+ Cl) and 1,3-bis(3,5-dicarboxyphenyl)imidazolium chloride (H4L+ Cl), to synthesize two nickel azolium-based MOFs, 1 and 2. The as-synthesis MOFs were characterized by PXRD, TGA, FE-SEM, HRTEM, FTIR and BET measurements. By applying 1 and 2 in liquid phase adsorption of charged molecules of dyes, they successfully exhibit remarkable efficiency for adsorptive removal of anionic dyes, Methyl orange (MO), Congo red (CR), and Orange II sodium salt (OS), from aqueous solution. The framework proves efficient in photocatalytic degradation of anionic dye. Furthermore, in the gaseous phase adsorption, 1 and 2 selectively adsorb CO2 over CH4 due to the higher quadrupole moment of CO2. Overall, the results show that azolium-based MOFs have potential applications for adsorptive removal of charged organic contaminants from both aqueous and gaseous environment. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Colloid and Interface Science | ||
| 463 | |t Vol. 519 |v [P. 214-223] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a dye | |
| 610 | 1 | |a gaseous molecule | |
| 610 | 1 | |a adsorption | |
| 610 | 1 | |a photocatalysis | |
| 610 | 1 | |a красители | |
| 610 | 1 | |a адсорбция | |
| 610 | 1 | |a фотокатализ | |
| 701 | 1 | |a Chizoba |b I. E. |g Ezugwu | |
| 701 | 0 | |a Md. Ali Asraf | |
| 701 | 0 | |a Xiao Li | |
| 701 | 0 | |a Liu Shengwei | |
| 701 | 0 | |a Kao Chih-Ming | |
| 701 | 1 | |a Zhuiykov |b S. V. |g Sergey | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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