Study on reduction behavior of two-component FeMgO oxide system prepared via a sol-gel technique; International Journal of Hydrogen Energy; Vol. 42, iss. 52
| Parent link: | International Journal of Hydrogen Energy Vol. 42, iss. 52.— 2017.— [P. 30543-30549] |
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| Autor corporatiu: | , |
| Altres autors: | , , , , , |
| Sumari: | Title screen Two-component FeMgO oxide system was prepared via sol-gel technique. An aqueous solution of iron nitrate was used to hydrolyze the magnesium methoxide instead of distilled water. The iron loading in a final sample was 15 wt% with respect to Fe2O3. The method was shown to provide a uniform distribution of iron oxide within MgO matrix. The sample was characterized by means of a low-temperature nitrogen adsorption and scanning electron microscopy. Reduction behavior of the sample was studied in a temperature-programmed regime using hydrogen as a reducing agent. In order to follow the possible phase transformations, the sample was examined by an in situ X-ray diffraction analysis in both reductive and oxidative atmospheres within the temperature range of 25–700 °C. It was found that after the first cycle of reduction/re-oxidation, the sample stabilizes in a novel state, and hydrogen uptake profiles of further cycles of reductive/oxidative treatment become completely reproducible. According to X-ray diffraction data, the sample consists of small particles (9 nm) of Fe3O4 phase well-dispersed within the structure of nanocrystalline MgO. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1016/j.ijhydene.2017.11.036 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=657770 |
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| 200 | 1 | |a Study on reduction behavior of two-component FeMgO oxide system prepared via a sol-gel technique |f T. M. Karnaukho [et al.] | |
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| 300 | |a Title screen | ||
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| 330 | |a Two-component FeMgO oxide system was prepared via sol-gel technique. An aqueous solution of iron nitrate was used to hydrolyze the magnesium methoxide instead of distilled water. The iron loading in a final sample was 15 wt% with respect to Fe2O3. The method was shown to provide a uniform distribution of iron oxide within MgO matrix. The sample was characterized by means of a low-temperature nitrogen adsorption and scanning electron microscopy. Reduction behavior of the sample was studied in a temperature-programmed regime using hydrogen as a reducing agent. In order to follow the possible phase transformations, the sample was examined by an in situ X-ray diffraction analysis in both reductive and oxidative atmospheres within the temperature range of 25–700 °C. It was found that after the first cycle of reduction/re-oxidation, the sample stabilizes in a novel state, and hydrogen uptake profiles of further cycles of reductive/oxidative treatment become completely reproducible. According to X-ray diffraction data, the sample consists of small particles (9 nm) of Fe3O4 phase well-dispersed within the structure of nanocrystalline MgO. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t International Journal of Hydrogen Energy | ||
| 463 | |t Vol. 42, iss. 52 |v [P. 30543-30549] |d 2017 | ||
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| 701 | 1 | |a Karnaukho |b T. M. |g Timofey Mikhaylovich | |
| 701 | 1 | |a Vedyagin |b A. A. |c Chemist |c Chief Expert of Tomsk Polytechnic University, Candidate of chemical sciences |f 1975- |g Aleksey Anatolievich |3 (RuTPU)RU\TPU\pers\36694 | |
| 701 | 1 | |a Cherepanova |b S. V. |g Svetlana | |
| 701 | 1 | |a Rogov |b V. A. |g Vladimir | |
| 701 | 1 | |a Stoyanovskii |b V. O. |g Vladimir | |
| 701 | 1 | |a Mishakov |b I. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, candidate of chemical sciences |f 1977- |g Iljya Vladimirovich |3 (RuTPU)RU\TPU\pers\36375 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа энергетики |b Научно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова) |3 (RuTPU)RU\TPU\col\23504 |
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