Hydrogen absorption by Ti-implanted Zr-1Nb alloy; International Journal of Hydrogen Energy; Vol. 43, iss. 4

Hydrogen absorption by Ti-implanted Zr-1Nb alloy; International Journal of Hydrogen Energy; Vol. 43, iss. 4

Dettagli Bibliografici
Parent link:	International Journal of Hydrogen Energy Vol. 43, iss. 4.— 2017.— [P. 2484-2491]
Ente Autore:	Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение экспериментальной физики
Altri autori:	Kashkarov E. B. Egor Borisovich, Nikitenkov N. N. Nikolai Nikolaevich, Sutygina A. N. Alina Nikolaevna, Obrosov A. Aleksey, Manakhov A. M. Anton Mikhaylovich, Polcak J. Josef, Weifs S. Sabine
Riassunto:	Title screen This paper describes the hydrogenation behavior of Zr-1Nb alloy Ti-implanted by plasma immersion ion implantation (PIII). Hydrogen sorption kinetics of the Ti-modified alloy was investigated under gas-phase hydrogenation at 400 °C for 1 h. The influence of implantation time on the protective properties of the modified layer was shown. The lowest hydrogen absorption as well as the highest hydrogen trapping efficiency was achieved after PIII for 30 min. The main contribution to the reduction of hydrogen permeation is the formation of an oxide layer consisting of mixed TiO2 and ZrO2 on the modified surface of the alloy. X-ray photoelectron spectroscopy (XPS) revealed that PIII titanium oxide exists on the surface in the form of TiO2, which transforms to mixed Ti2O3 and TiO2 after hydrogenation. The thickness of the modified layer increases with implantation time that improves the efficiency of hydrogen trapping. All the absorbed hydrogen is gradually distributed in the modified layer and no hydrides are formed after hydrogenation in Ti-modified Zr-1Nb for 15 and 30 min. Режим доступа: по договору с организацией-держателем ресурса
Lingua:	inglese
Pubblicazione:	2017
Soggetti:	электронный ресурс труды учёных ТПУ имплантация цирконий титан гидрогенизация рентгеновская спектроскопия излучение дифракция
Accesso online:	https://doi.org/10.1016/j.ijhydene.2017.12.003
Natura:	Elettronico Capitolo di libro
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=657768

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