The simplest and fascinating metal–organic polyhedra: Tetrahedra

The simplest and fascinating metal–organic polyhedra: Tetrahedra

Bibliographic Details
Parent link:Coordination Chemistry Reviews
Vol. 353.— 2017.— [P. 180–200]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Zhaoxuan Wu, Kui Zhou, Ivanov A. V. Andrey, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Metal-organic polyhedra (MOPs) have attracted great interest in the past decade. As a new series of nano-material, MOPs have high outer and inner specific surface areas and are able to be applied in different areas such as catalysis, gas sequestration, drug delivery, molecule sensing, etc. In this review, the focus is made on the design and synthetic strategies approaching edge-bridged tetrahedra MnL6 and face-capped tetrahedra MnL4. Besides the synthesis, structure, and properties of tetrahedral self-assemblies are also considered, while tetrahedra will be compared with other complicated multinuclear constructions. The discussion of how the properties of tetrahedral cages can be altered by varying employed subcomponents is made. Moreover, the multifarious host-guest system and behavior of metal-organic tetrahedral self-assemblies for catalytic applications are addressed in details.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2017
Subjects:
электронный ресурс
труды учёных ТПУ
metal-organic polyhedral
tetrahedra
self-assembly
host-guest
catalysis
металлоорганические соединения
полиэдры
тетраэдры
самоорганизация
катализ
Online Access:https://doi.org/10.1016/j.ccr.2017.10.008
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656800

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