Investigation of the ro-vibrational energy structure of (0101, F1) and (0101, F2) states of the 28SiH4 molecule; Atmospheric and Oceanic Optics; Vol. 30, iss. 6
| Parent link: | Atmospheric and Oceanic Optics: Scientific Journal Vol. 30, iss. 6.— 2017.— [P. 502-507] |
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| Autor principal: | |
| Autor corporatiu: | |
| Sumari: | Title screen An analysis of the high-resolution vibrational-rotational IR spectrum of ν2 + ν4 (F1) and ν2 + ν4(F2) bending absorption bands of the 28SiH4 molecule is carried out for the first time using the SPHETOM software. Approximately 618 experimental transitions with Jmax = 8 are assigned to ν2 + ν4 (F1) and ν2 + ν4 (F2) bands. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for these vibrational bands are derived from the weighted fit of experimental line positions. The set of parameters obtained reproduces the initial experimental data with an accuracy close to the experimental uncertainties drms = 8 × 10-4 cm-1. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1134/S1024856017060124 |
| Format: | MixedMaterials Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656778 |
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| 200 | 1 | |a Investigation of the ro-vibrational energy structure of (0101, F1) and (0101, F2) states of the 28SiH4 molecule |f N. I. Raspopova | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 29 tit.] | ||
| 330 | |a An analysis of the high-resolution vibrational-rotational IR spectrum of ν2 + ν4 (F1) and ν2 + ν4(F2) bending absorption bands of the 28SiH4 molecule is carried out for the first time using the SPHETOM software. Approximately 618 experimental transitions with Jmax = 8 are assigned to ν2 + ν4 (F1) and ν2 + ν4 (F2) bands. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for these vibrational bands are derived from the weighted fit of experimental line positions. The set of parameters obtained reproduces the initial experimental data with an accuracy close to the experimental uncertainties drms = 8 × 10-4 cm-1. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Atmospheric and Oceanic Optics |o Scientific Journal | ||
| 463 | |t Vol. 30, iss. 6 |v [P. 502-507] |d 2017 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a bending vibrations | |
| 610 | 1 | |a overtones | |
| 610 | 1 | |a tetrahedral splittings | |
| 610 | 1 | |a resonance interactions | |
| 610 | 1 | |a изгибные колебания | |
| 610 | 1 | |a обертоны | |
| 610 | 1 | |a тетраэдрические расщепления | |
| 610 | 1 | |a резонансные взаимодействия | |
| 700 | 1 | |a Raspopova |b N. I. |c physicist |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences |f 1990- |g Natalya Ivanovna |3 (RuTPU)RU\TPU\pers\34080 |9 17636 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет (ТПУ) |b Физико-технический институт (ФТИ) |b Кафедра экспериментальной физики (ЭФ) |3 (RuTPU)RU\TPU\col\21255 |
| 801 | 2 | |a RU |b 63413507 |c 20180221 |g RCR | |
| 856 | 4 | |u https://doi.org/10.1134/S1024856017060124 | |
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