Zn@ZIF-67 as Catalysts for the Knoevenagel Condensation of Aldehyde Derivatives with Malononitrile

Zn@ZIF-67 as Catalysts for the Knoevenagel Condensation of Aldehyde Derivatives with Malononitrile

Bibliographic Details
Parent link:Catalysis Letters
Vol. 147, iss. 9.— 2017.— [P. 2410-2420]
Main Author: Zanon A. Adriano
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Chaemchuen S. Somboon, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Three different bimetallic zinc-cobalt zeolitic imidazolate frameworks (ZIFs) were successfully synthesized at room temperature in water through a green and simple procedure and tested as catalysts for the Knoevenagel condensation reaction between p-Br-benzaldehyde and malononitrile as model reaction. The materials were characterized with various techniques (XRD, ICP-AES, SEM, N2 adsorption–desorption, TGA) and displayed excellent activities and selectivities. Moreover, the crystalline structure was preserved and the catalysts could be reused at least four times with negligible loss of activity.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2017
Subjects:
электронный ресурс
труды учёных ТПУ
гетерогенный катализ
металлоорганические комплексы
конденсация
каркасы
Online Access:https://doi.org/10.1007/s10562-017-2153-y
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656672

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