Zn@ZIF-67 as Catalysts for the Knoevenagel Condensation of Aldehyde Derivatives with Malononitrile
| Parent link: | Catalysis Letters Vol. 147, iss. 9.— 2017.— [P. 2410-2420] |
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| Outros Autores: | , |
| Resumo: | Title screen Three different bimetallic zinc-cobalt zeolitic imidazolate frameworks (ZIFs) were successfully synthesized at room temperature in water through a green and simple procedure and tested as catalysts for the Knoevenagel condensation reaction between p-Br-benzaldehyde and malononitrile as model reaction. The materials were characterized with various techniques (XRD, ICP-AES, SEM, N2 adsorption–desorption, TGA) and displayed excellent activities and selectivities. Moreover, the crystalline structure was preserved and the catalysts could be reused at least four times with negligible loss of activity. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | inglês |
| Publicado em: |
2017
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| Acesso em linha: | https://doi.org/10.1007/s10562-017-2153-y |
| Formato: | Recurso Electrónico Capítulo de Livro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656672 |
| Resumo: | Title screen Three different bimetallic zinc-cobalt zeolitic imidazolate frameworks (ZIFs) were successfully synthesized at room temperature in water through a green and simple procedure and tested as catalysts for the Knoevenagel condensation reaction between p-Br-benzaldehyde and malononitrile as model reaction. The materials were characterized with various techniques (XRD, ICP-AES, SEM, N2 adsorption–desorption, TGA) and displayed excellent activities and selectivities. Moreover, the crystalline structure was preserved and the catalysts could be reused at least four times with negligible loss of activity. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1007/s10562-017-2153-y |