Physicochemical properties and catalytic activity of metal–carbon carrier composite materials

Physicochemical properties and catalytic activity of metal–carbon carrier composite materials

Bibliographic Details
Parent link:Russian Journal of Physical Chemistry A: Scientific Journal
Vol. 91, iss. 7.— 2017.— [P. 1197-1203]
Corporate Authors: Национальный исследовательский Томский политехнический университет (ТПУ) Отдел организации НИОКР, Национальный исследовательский Томский политехнический университет (ТПУ) Юргинский технологический институт (филиал) (ЮТИ) Кафедра сварочного производства (КСП)
Other Authors: Kobotaeva N. S. Nataljya Stanislavovna, Skorokhodova T. S. Tatjyana Sergeevna, Razdjyakonova G. I. Galina Ivanovna, Poleshchuk O. Kh. Oleg Khemovich
Summary:Title screen
Composite metal–carbon materials are created on the basis of different kinds of carbon (multiwall carbon nanotubes, carbon black, Sibunit carbon–carbon material) and metals (Ag, Ni, Co), and their physicochemical and catalytic properties are investigated. It is shown that interaction between metals and carbon carriers proceeds not only with the functional groups on the surfaces of the carriers, but also through a system of–C–C–conjugated bonds. Silver deposited on the surface of a carbon carrier has a crystalline structure (dcr = 10–15 nm), while nickel has an amorphous lamellar structure. Based on quantum-chemical calculations using the density functional theory, it is shown that cumene oxidation occurs via a homogeneous–heterogeneous mechanism.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2017
Subjects:
электронный ресурс
труды учёных ТПУ
композиционные материалы
углеродные материалы
сажа
катализаторы
Online Access:https://doi.org/10.1134/S0036024417070172
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656510

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