Benzene alkylation with ethylene: The way to increase the process efficiency; Chemical Engineering and Processing: Process Intensification; Vol. 120

Dettagli Bibliografici
Parent link:Chemical Engineering and Processing: Process Intensification
Vol. 120.— 2017.— [P. 234-240]
Autore principale: Khlebnikova E. S. Elena Sergeevna
Ente Autore: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра химической технологии топлива и химической кибернетики (ХТТ)
Altri autori: Ivashkina E. N. Elena Nikolaevna, Dolganova I. O. Irena Olegovna
Riassunto:Title screen
Ethylbenzene is the main ingredient to obtain textile fabric, plastics, detergents, etc. The current industrial ethylbenzene production method includes mainly zeolite catalyst. However, liquid acidic catalysts such are also still used. In contrast to zeolite alkylation technology, there is much less information on how to improve the alkylation unit performance. The present research investigates the possibility of obtaining this goal by intensifying the reagents mixing before the alkylation reactor. We present the results of the mixing chamber hydrodynamic modeling clearly showing that it is reasonable to change the way of reagents injection: benzene-into the first, circulating catalyst into the second and fresh catalyst into the third pipe branch along the ethylene flow. This will intensify the mixing process and reduce the size of the catalyst droplets bringing the alkylation from diffusion into kinetic region. This variant of reagents injection will also ensure the uniformity of reagents distribution. The possibility to decrease the circulating catalyst flow rate from 8000 to 5000 (kg h?1) without changing the mixing efficiency also demonstrates the feasibility of the proposed solution.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2017
Soggetti:
Accesso online:https://doi.org/10.1016/j.cep.2017.07.002
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=656413

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200 1 |a Benzene alkylation with ethylene: The way to increase the process efficiency  |f E. S. Khlebnikova, E. N. Ivashkina, I. O. Dolganova 
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300 |a Title screen 
320 |a [References: 32 tit.] 
330 |a Ethylbenzene is the main ingredient to obtain textile fabric, plastics, detergents, etc. The current industrial ethylbenzene production method includes mainly zeolite catalyst. However, liquid acidic catalysts such are also still used. In contrast to zeolite alkylation technology, there is much less information on how to improve the alkylation unit performance. The present research investigates the possibility of obtaining this goal by intensifying the reagents mixing before the alkylation reactor. We present the results of the mixing chamber hydrodynamic modeling clearly showing that it is reasonable to change the way of reagents injection: benzene-into the first, circulating catalyst into the second and fresh catalyst into the third pipe branch along the ethylene flow. This will intensify the mixing process and reduce the size of the catalyst droplets bringing the alkylation from diffusion into kinetic region. This variant of reagents injection will also ensure the uniformity of reagents distribution. The possibility to decrease the circulating catalyst flow rate from 8000 to 5000 (kg h?1) without changing the mixing efficiency also demonstrates the feasibility of the proposed solution. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Chemical Engineering and Processing: Process Intensification 
463 |t Vol. 120  |v [P. 234-240]  |d 2017 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a Hydrodynamics 
610 1 |a Mixing 
610 1 |a Optimization 
610 1 |a Droplets 
610 1 |a Mixers 
610 1 |a Simulation 
610 1 |a гидродинамика 
610 1 |a моделирование 
610 1 |a оптимизация 
700 1 |a Khlebnikova  |b E. S.  |c Chemical Engineer  |c assistant of Tomsk Polytechnic University  |f 1990-  |g Elena Sergeevna  |3 (RuTPU)RU\TPU\pers\35846 
701 1 |a Ivashkina  |b E. N.  |c Chemical Engineer  |c Professor of Tomsk Polytechnic University, Doctor of technical sciences  |f 1983-  |g Elena Nikolaevna  |3 (RuTPU)RU\TPU\pers\31275  |9 15453 
701 1 |a Dolganova  |b I. O.  |c chemist  |c Associate Scientist of Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences  |f 1988-  |g Irena Olegovna  |3 (RuTPU)RU\TPU\pers\31271  |9 15449 
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