Dynamic NMR under nonstationary conditions: Theoretical model, numerical calculation, and potential of application

Dades bibliogràfiques
Parent link:The Journal of Chemical Physics
Vol. 145, iss. 5.— 2016.— [054201, 10 р.]
Autor principal: Babailov S. P. Sergey Pavlovich
Autor corporatiu: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ)
Altres autors: Purtov P. A. Petr Aleksandrovich, Fomin E. S. Eduard Stanislavovich
Sumari:Title screen
An expression has been derived for the time dependence of the NMR line shape for systems with multi-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematical programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:anglès
Publicat: 2016
Matèries:
Accés en línia:http://dx.doi.org/10.1063/1.4959592
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655971

Ítems similars