First rotational analysis of the (111) and (021) vibrational state of S16O18O from the “hot” ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2bands; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 202
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 202.— 2017.— [P. 98-103] |
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| Συγγραφή απο Οργανισμό/Αρχή: | |
| Άλλοι συγγραφείς: | , , , , , , , |
| Περίληψη: | Title screen The rotational structure of the (111) and (021) vibrational states is determined for the first time from the high resolution analysis of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands. The 480 and 74 transitions of these bands (Jmax/Kamax = 45/14 and 15/12 respectively) were assigned in the spectra, which have been recorded with the Bruker IFS 120 Fourier transform infrared (FTIR) spectrometer. A weighted fit analysis allowed us to generate a set of 5 fitted parameters for the (111) state and 4 fitted parameters for the (021) state. Calculation with the 9 parameters, obtained from the fit, reproduces the initial 363 energy values (about 550 assigned experimental transitions) of two vibrational states with the drms deviations of 3.2×10−4 cm−1, which is comparable with the experimental uncertainties of very weak transitions of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands in our experiment. Режим доступа: по договору с организацией-держателем ресурса |
| Γλώσσα: | Αγγλικά |
| Έκδοση: |
2017
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| Θέματα: | |
| Διαθέσιμο Online: | https://doi.org/10.1016/j.jqsrt.2017.07.029 |
| Μορφή: | Ηλεκτρονική πηγή Κεφάλαιο βιβλίου |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655888 |
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| 200 | 1 | |a First rotational analysis of the (111) and (021) vibrational state of S16O18O from the “hot” ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2bands |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 102-103 (40 tit.)] | ||
| 330 | |a The rotational structure of the (111) and (021) vibrational states is determined for the first time from the high resolution analysis of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands. The 480 and 74 transitions of these bands (Jmax/Kamax = 45/14 and 15/12 respectively) were assigned in the spectra, which have been recorded with the Bruker IFS 120 Fourier transform infrared (FTIR) spectrometer. A weighted fit analysis allowed us to generate a set of 5 fitted parameters for the (111) state and 4 fitted parameters for the (021) state. Calculation with the 9 parameters, obtained from the fit, reproduces the initial 363 energy values (about 550 assigned experimental transitions) of two vibrational states with the drms deviations of 3.2×10−4 cm−1, which is comparable with the experimental uncertainties of very weak transitions of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands in our experiment. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 202 |v [P. 98-103] |d 2017 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a 32S16O18O молекула | |
| 610 | 1 | |a горячие группы | |
| 610 | 1 | |a параметры | |
| 610 | 1 | |a вращательный анализ | |
| 610 | 1 | |a колебательные состояния | |
| 610 | 1 | |a двуокись серы | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Zyatkova (Ziatkova) |b A. G. |c Physicist |c Engineer of the Department of Tomsk Polytechnic University |f 1991- |g Anastasiya Georgievna |3 (RuTPU)RU\TPU\pers\37482 | |
| 701 | 1 | |a Склярова |b Е. А. |c физик |c доцент Томского политехнического университета, кандидат педагогических наук |f 1972- |g Елена Александровна |3 (RuTPU)RU\TPU\pers\24507 |9 10826 | |
| 701 | 1 | |a Kuznetsov |b S. I. |c physicist |c associate professor of Tomsk polytechnic university, candidate of technical sciences (PhD) |f 1952- |g Sergey Ivanovich |3 (RuTPU)RU\TPU\pers\30071 | |
| 701 | 1 | |a Sydow |b C. |g Christian | |
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